Rhodium-Catalyzed Regioselective Addition of N-Hydroxyl Imides to Internal Alkynes

IF 2.4 4区化学 Q3 CHEMISTRY, MULTIDISCIPLINARY

Israel Journal of Chemistry Pub Date : 2026-04-02 DOI:10.1002/ijch.70014

Zi Liu, Bernhard Breit

引用次数: 0

Abstract

An intermolecular rhodium-catalyzed regioselective addition of N-hydroxyl imides to internal alkynes leads to branched O-allyl compounds, which can be readily transformed to allylic alcohols and O-allyl hydroxylamines after deprotection. Isotopic labeling experiments suggest a plausible reaction mechanism.

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铑催化内炔上n -羟基亚胺的区域选择性加成

分子间铑催化的n -羟基亚胺在内炔上的选择性加成反应生成支链的o -烯丙基化合物，这些化合物在脱保护后很容易转化为烯丙醇和o -烯丙基羟胺。同位素标记实验提出了一种合理的反应机制。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Israel Journal of Chemistry 化学-化学综合

CiteScore

6.20

自引率

0.00%

发文量

审稿时长

6-12 weeks

期刊介绍： The fledgling State of Israel began to publish its scientific activity in 1951 under the general heading of Bulletin of the Research Council of Israel, which quickly split into sections to accommodate various fields in the growing academic community. In 1963, the Bulletin ceased publication and independent journals were born, with Section A becoming the new Israel Journal of Chemistry. The Israel Journal of Chemistry is the official journal of the Israel Chemical Society. Effective from Volume 50 (2010) it is published by Wiley-VCH. The Israel Journal of Chemistry is an international and peer-reviewed publication forum for Special Issues on timely research topics in all fields of chemistry: from biochemistry through organic and inorganic chemistry to polymer, physical and theoretical chemistry, including all interdisciplinary topics. Each topical issue is edited by one or several Guest Editors and primarily contains invited Review articles. Communications and Full Papers may be published occasionally, if they fit with the quality standards of the journal. The publication language is English and the journal is published twelve times a year.