Electrochemical Corrosion and Safety Hazards in Sustainable Batteries: Corrosion Mechanisms, Safety Challenges, and Protection

IF 36.3 1区材料科学 Q1 Engineering

Nano-Micro Letters Pub Date : 2026-04-15 DOI:10.1007/s40820-026-02178-9

Chandrabhan Verma, Imad Barsoum, Akram Alfantazi, Kyong Yop Rhee

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引用次数: 0

Abstract

Highlights

This review provides the first comprehensive collection of electrochemical corrosion mechanisms in Zn-, Al-, Mg-, Na-, organic-, and bio-based batteries, highlighting their safety and hazardous effects of corrosion in sustainable batteries.
This review uniquely presents the connection of electrochemical corrosion with dendrite formation, hydrogen evolution, impedance growth, recycling challenges, capacity fading, and safety hazards.
This provides a next-generation solution, such as corrosion inhibitors, bio-derived additives, metal–organic frameworks, deep eutectic solvents, ionic liquids, gel electrolytes, and interfacial and surface engineering approaches.

查看原文本刊更多论文

可持续电池中的电化学腐蚀和安全危害：腐蚀机制、安全挑战和保护。

随着向可持续能源的快速转型，对高性能、安全和环保的电池技术的需求不断提高。锌、镁、钠、铝、铁、有机和生物基体系相对于传统的资源密集型和有毒替代品具有许多优势。然而，它们的实际应用受到电化学腐蚀敏感性的极大挑战，这对它们的效率、寿命、安全性、可回收性和可逆性产生了不利影响。腐蚀是下一代储能系统发展的最重要和最持久的障碍之一。这篇综述全面介绍了不同可持续电池系统的统一腐蚀机制，并详细介绍了点蚀、均匀、原电、晶间和钝化相关的降解途径。本文对锌、铝、镁等阳极在不同电解质中的降解机理进行了独特的比较。缓蚀策略，包括表面钝化、表面工程、合金化、使用表面活性剂和聚合物基薄膜、离子液体、深共晶溶剂、金属有机框架、杂环化合物和生物基多功能缓蚀剂，已经得到了全面的调查。这些抑制剂抑制循环寿命的增加，达到90%以上的抑制效率。最后，综述强调了分子级缓蚀剂的设计、界面工程、实时腐蚀测试、先进电解质和前瞻性方向，所有这些都是开发可持续、稳定的储能系统所必需的。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Nano-Micro Letters NANOSCIENCE & NANOTECHNOLOGY-MATERIALS SCIENCE, MULTIDISCIPLINARY

CiteScore

32.60

自引率

4.90%

发文量

981

审稿时长

1.1 months

期刊介绍： Nano-Micro Letters is a peer-reviewed, international, interdisciplinary, and open-access journal published under the SpringerOpen brand. Nano-Micro Letters focuses on the science, experiments, engineering, technologies, and applications of nano- or microscale structures and systems in various fields such as physics, chemistry, biology, material science, and pharmacy.It also explores the expanding interfaces between these fields. Nano-Micro Letters particularly emphasizes the bottom-up approach in the length scale from nano to micro. This approach is crucial for achieving industrial applications in nanotechnology, as it involves the assembly, modification, and control of nanostructures on a microscale.