Access to Cyclobutanones by a Photoredox‐Catalyzed Deoxygenation/Wolff Rearrangement/Cycloadditions Cascade Reaction

IF 2.7 4区化学 Q1 CHEMISTRY, ORGANIC

Asian Journal of Organic Chemistry Pub Date : 2026-04-01 Epub Date: 2026-04-29 DOI:10.1002/ajoc.70398

Hui Yang , Ying Lian , Yan Li , Wenhui Zhang , Shuqian Wang , Ni Yang , Biao Xu , Guoliang Lin , Zeyu Song , Guo Wei

引用次数: 0

Abstract

Novel synthesis of cyclobutanones is realized through a visible‐light catalyzed deoxygenation‐Wolff‐cycloaddition cascade reaction. Substituents of both electron‐donating and electron‐withdrawing properties can be well tolerated. This strategy provides a straightforward access to substituted cyclobutanones from readily available \xF0\x9D\x9B\xBC‐diketones under mild conditions.

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光氧化还原催化脱氧/Wolff重排/环加成级联反应获得环丁酮

通过可见光催化脱氧- wolff -环加成级联反应，实现了环丁酮类化合物的合成。具有供电子和吸电子性质的取代基都能很好地耐受。该策略提供了在温和条件下从现成的𝛼-diketones中直接获得取代环丁酮的方法。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Asian Journal of Organic Chemistry CHEMISTRY, ORGANIC-

CiteScore

4.70

自引率

3.70%

发文量

372

期刊介绍： Organic chemistry is the fundamental science that stands at the heart of chemistry, biology, and materials science. Research in these areas is vigorous and truly international, with three major regions making almost equal contributions: America, Europe and Asia. Asia now has its own top international organic chemistry journal—the Asian Journal of Organic Chemistry (AsianJOC) The AsianJOC is designed to be a top-ranked international research journal and publishes primary research as well as critical secondary information from authors across the world. The journal covers organic chemistry in its entirety. Authors and readers come from academia, the chemical industry, and government laboratories.