Direct azido-sulfenylation/-selenylation of alkenes: a straightforward route to β-azido sulfides and selenides

IF 1.7 3区化学 Q3 CHEMISTRY, MULTIDISCIPLINARY

Journal of Sulfur Chemistry Pub Date : 2026-03-04 Epub Date: 2025-11-01 DOI:10.1080/17415993.2025.2572380

Ahmed Kareem Obaid Aldulaimi , Huseyn Imanov , Shakir Mahmood Saeed , Wadhah Hasan Alkhazali , Waam Mohammed Taher , Mariem Alwan , Mahmood Jasem Jawad , Hiba Mushtaq , Esmail Vessally

引用次数: 0

Abstract

The direct difunctionalization of alkenes, a cheap and abundant feedstock, is one of the most powerful and sustainable strategies for concomitant introduction of two functional groups into the π system in a single operation. In this context, vicinal azido-sulfenylation/-selenylation of alkenes has emerged as a powerful and straightforward synthetic strategy for the efficient construction of β-azido sulfides and selenides that have found application in different fields. The purpose of this review is to summarize the available literature on the synthesis of β-azido sulfides and β-azido selenides through the direct azido-sulfenylation and azido-selenylation of alkenes, respectively, focusing on the published literature from 1987 to the present.

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烯的直接叠氮-磺酰化/-硒酰化：生成β-叠氮-硫化物和硒化物的直接途径

烯烃的直接双官能团化是一种廉价而丰富的原料，是在一次操作中将两个官能团同时引入π体系的最有效和可持续的策略之一。在这种背景下，邻叠氮基磺酰化/-硒化烯烃已成为一种强大而直接的合成策略，用于高效构建β-叠氮基硫化物和硒化物，并已在不同领域得到应用。本文主要综述了1987年至今通过直接叠氮-亚砜化和叠氮-硒化分别合成β-叠氮-硫化物和β-叠氮-硒化的文献。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Journal of Sulfur Chemistry CHEMISTRY, MULTIDISCIPLINARY-

CiteScore

4.10

自引率

9.10%

发文量

审稿时长

6-12 weeks

期刊介绍： The Journal of Sulfur Chemistry is an international journal for the dissemination of scientific results in the rapidly expanding realm of sulfur chemistry. The journal publishes high quality reviews, full papers and communications in the following areas: organic and inorganic chemistry, industrial chemistry, materials and polymer chemistry, biological chemistry and interdisciplinary studies directly related to sulfur science. Papers outlining theoretical, physical, mechanistic or synthetic studies pertaining to sulfur chemistry are welcome. Hence the target audience is made up of academic and industrial chemists with peripheral or focused interests in sulfur chemistry. Manuscripts that truly define the aims of the journal include, but are not limited to, those that offer: a) innovative use of sulfur reagents; b) new synthetic approaches to sulfur-containing biomolecules, materials or organic and organometallic compounds; c) theoretical and physical studies that facilitate the understanding of sulfur structure, bonding or reactivity; d) catalytic, selective, synthetically useful or noteworthy transformations of sulfur containing molecules; e) industrial applications of sulfur chemistry; f) unique sulfur atom or molecule involvement in interfacial phenomena; g) descriptions of solid phase or combinatorial methods involving sulfur containing substrates. Submissions pertaining to related atoms such as selenium and tellurium are also welcome. Articles offering routine heterocycle formation through established reactions of sulfur containing substrates are outside the scope of the journal.