Design and diffusion kinetics of cold-sprayed multilayer interlayers for low-temperature, short-time joining of SiC/GH3536

IF 7.9 2区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY
Materials Science and Engineering: A Pub Date : 2026-03-01 Epub Date: 2026-02-13 DOI:10.1016/j.msea.2026.149922
Gu Gong , Weiyuan Yu , Mingkang Wang , Yanzhen Li , Peng Liang
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引用次数: 0

Abstract

To achieve reliable joining between SiC ceramics and a nickel-based superalloy and thereby fully exploit the respective performance advantages of both materials, a Ti/Cu/Ni/Cu/Ti multilayer interlayer was fabricated by cold spray and used for joining SiC to GH3536 alloy. The effects of joining temperature and holding time on the microstructure and mechanical properties of the joints were systematically investigated, and the joint formation mechanism was analyzed. The results indicate that a diffusion-couple structure formed within the cold-sprayed interlayer during the joining process. Compared with conventional binary diffusion-couple models based on the Darken equation and the Arrhenius equation, this structure significantly enhances interdiffusion of elements, thereby reducing the required joining temperature and holding time. Reliable joining was achieved at 900 °C with a holding time of 5 min, while a maximum shear strength of 63.94 MPa was obtained at 920 °C for 5 min. Further analysis reveals that the Cu-Ti liquid phase formed during joining promotes wetting and bonding, whereas the Ni layer acts as a stress-buffer layer, effectively alleviating residual stresses in the joint region. This study provides a new and efficient approach for joining SiC ceramics and their composites with nickel-based alloys, and offers new insights into the joining of ceramic–metal dissimilar materials.
SiC/GH3536低温短时连接冷喷涂多层中间层设计及扩散动力学
为了实现SiC陶瓷与镍基高温合金的可靠连接,充分发挥两种材料各自的性能优势,采用冷喷涂法制备了Ti/Cu/Ni/Cu/Ti多层夹层,用于SiC与GH3536合金的连接。系统研究了连接温度和保温时间对接头组织和力学性能的影响,并分析了接头的形成机理。结果表明:冷喷涂层在接合过程中形成了扩散偶结构;与传统的基于Darken方程和Arrhenius方程的二元扩散偶模型相比,该结构显著增强了元素的相互扩散,从而降低了连接温度和保温时间。在900℃保温5 min的条件下获得了可靠的连接,在920℃保温5 min的条件下获得了63.94 MPa的最大抗剪强度。进一步分析表明,在连接过程中形成的Cu-Ti液相促进了润湿和键合,而Ni层则起到了应力缓冲层的作用,有效地缓解了连接区域的残余应力。本研究为SiC陶瓷及其复合材料与镍基合金的连接提供了一种新的、有效的方法,并为陶瓷-金属异种材料的连接提供了新的见解。
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来源期刊
Materials Science and Engineering: A
Materials Science and Engineering: A 工程技术-材料科学:综合
CiteScore
11.50
自引率
15.60%
发文量
1811
审稿时长
31 days
期刊介绍: Materials Science and Engineering A provides an international medium for the publication of theoretical and experimental studies related to the load-bearing capacity of materials as influenced by their basic properties, processing history, microstructure and operating environment. Appropriate submissions to Materials Science and Engineering A should include scientific and/or engineering factors which affect the microstructure - strength relationships of materials and report the changes to mechanical behavior.
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