Ionic, Covalent, and Covalent-Ionic Chitosan Hydrogels with 5-Norbornene-2,3-Dicarboxylic Crosslinker

IF 1 4区 化学 Q4 POLYMER SCIENCE
G. R. Mingaleeva, T. D. Abdurahimov, I. N. Korolev, V. Z. Mingaleev
{"title":"Ionic, Covalent, and Covalent-Ionic Chitosan Hydrogels with 5-Norbornene-2,3-Dicarboxylic Crosslinker","authors":"G. R. Mingaleeva,&nbsp;T. D. Abdurahimov,&nbsp;I. N. Korolev,&nbsp;V. Z. Mingaleev","doi":"10.1134/S1560090425601244","DOIUrl":null,"url":null,"abstract":"<p>Ionic, covalent, covalent-ionic hydrogels of chitosan and 5-norbornene-dicarboxylic acid or its anhydride as crosslinker were obtained. The developed synthetic routes of ionic and covalent crosslinking of chitosan make it possible to have a significant effect on the molecular structure of polymer networks of hydrogels, their rheological properties, and ability to swell at various pH. The concentration of the crosslinker is an additional factor in the directional regulation of the listed properties of hydrogels in intervals, the boundaries of which are set by the nature of chemical bonds in crosslinkers. The results obtained make it possible to predict and select the optimal samples for the development and improvement of hydrogel materials based on chitosan for biomedical applications.</p>","PeriodicalId":739,"journal":{"name":"Polymer Science, Series B","volume":"67 3","pages":""},"PeriodicalIF":1.0000,"publicationDate":"2026-02-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Polymer Science, Series B","FirstCategoryId":"1","ListUrlMain":"https://link.springer.com/article/10.1134/S1560090425601244","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"POLYMER SCIENCE","Score":null,"Total":0}
引用次数: 0

Abstract

Ionic, covalent, covalent-ionic hydrogels of chitosan and 5-norbornene-dicarboxylic acid or its anhydride as crosslinker were obtained. The developed synthetic routes of ionic and covalent crosslinking of chitosan make it possible to have a significant effect on the molecular structure of polymer networks of hydrogels, their rheological properties, and ability to swell at various pH. The concentration of the crosslinker is an additional factor in the directional regulation of the listed properties of hydrogels in intervals, the boundaries of which are set by the nature of chemical bonds in crosslinkers. The results obtained make it possible to predict and select the optimal samples for the development and improvement of hydrogel materials based on chitosan for biomedical applications.

Abstract Image

含5-降冰片烯-2,3-二羧基交联剂的离子、共价和共价离子壳聚糖水凝胶
以壳聚糖为交联剂,以5-降冰片烯二羧酸或其酸酐为交联剂,制备了离子、共价、共价离子水凝胶。壳聚糖离子交联和共价交联的合成路线的发展,使其有可能对水凝胶聚合物网络的分子结构、流变性能和在不同ph值下的膨胀能力产生重大影响。交联剂的浓度是水凝胶在间隔中所列性质的定向调节的另一个因素,其边界是由交联剂的化学键的性质决定的。研究结果为开发和改进医用壳聚糖水凝胶材料提供了预测和选择最佳样品的可能。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
求助全文
约1分钟内获得全文 求助全文
来源期刊
Polymer Science, Series B
Polymer Science, Series B 化学-高分子科学
CiteScore
1.80
自引率
8.30%
发文量
58
审稿时长
>0 weeks
期刊介绍: Polymer Science, Series B is a journal published in collaboration with the Russian Academy of Sciences. Series B experimental and theoretical papers and reviews dealing with the synthesis, kinetics, catalysis, and chemical transformations of macromolecules, supramolecular structures, and polymer matrix-based composites (6 issues a year). All journal series present original papers and reviews covering all fundamental aspects of macromolecular science. Contributions should be of marked novelty and interest for a broad readership. Articles may be written in English or Russian regardless of country and nationality of authors. All manuscripts are peer reviewed
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
copy
已复制链接
快去分享给好友吧!
我知道了
右上角分享
点击右上角分享
0
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:604180095
Book学术官方微信
小红书