Electrical Resistivity of Equiatomic High-Entropy CoCrFeNi Alloy at High Temperatures

IF 0.3 Q4 METALLURGY & METALLURGICAL ENGINEERING
V. A. Bykov, D. A. Yagodin, T. V. Kulikova, K. Yu. Shunayev
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Abstract

The temperature dependence of the specific electrical resistivity of the high-entropy equiatomic CoCrFeNi alloy was studied in the range of 1100–1900 K using the contactless rotating magnetic field method, including the solid and liquid states. It was found that the electrical resistivity increases linearly with temperature, and at the melting point, there is an abrupt change toward an increase in its value. High absolute electrical resistivity values and a low temperature coefficient of about 10–4 K–1 are retained in the condensed state. The temperature dependence of electrical resistivity obeys the Bloch–Grüneisen law, and the main scattering mechanism at high temperatures is associated with the defect crystal lattice and, to a lesser extent, with phonons. The behavior of the electrical resistivity of the disordered solid solution CoCrFeNi at high temperatures confirmed that the conductivity was metallic type.

Abstract Image

等原子高熵CoCrFeNi合金高温下的电阻率
采用无接触旋转磁场法研究了高熵等原子CoCrFeNi合金在1100 ~ 1900 K范围内的比电阻率与温度的关系,包括固态和液态。结果表明,电阻率随温度的升高呈线性增加,在熔点处,电阻率呈陡增趋势。在凝聚态下保持了较高的绝对电阻率值和约10-4 K-1的低温系数。电阻率的温度依赖性服从布洛赫-格拉尼森定律,高温下的主要散射机制与缺陷晶格有关,在较小程度上与声子有关。对无序固溶体CoCrFeNi在高温下的电阻率行为进行了研究,证实其电导率为金属型。
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来源期刊
Russian Metallurgy (Metally)
Russian Metallurgy (Metally) METALLURGY & METALLURGICAL ENGINEERING-
CiteScore
0.70
自引率
25.00%
发文量
140
期刊介绍: Russian Metallurgy (Metally)  publishes results of original experimental and theoretical research in the form of reviews and regular articles devoted to topical problems of metallurgy, physical metallurgy, and treatment of ferrous, nonferrous, rare, and other metals and alloys, intermetallic compounds, and metallic composite materials. The journal focuses on physicochemical properties of metallurgical materials (ores, slags, matters, and melts of metals and alloys); physicochemical processes (thermodynamics and kinetics of pyrometallurgical, hydrometallurgical, electrochemical, and other processes); theoretical metallurgy; metal forming; thermoplastic and thermochemical treatment; computation and experimental determination of phase diagrams and thermokinetic diagrams; mechanisms and kinetics of phase transitions in metallic materials; relations between the chemical composition, phase and structural states of materials and their physicochemical and service properties; interaction between metallic materials and external media; and effects of radiation on these materials.
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