Functional Doping of a Liquid Crystal Matrix for Photocontrolled Ordering of Nanocomposites

IF 0.8 Q3 Engineering
A. S. Plotnikova, Y. I. Derikov, Y. A. Egorov, A. S. Merekalov, O. N. Karpov, L. A. Golovan
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引用次数: 0

Abstract

The phase behavior of a liquid-crystal (LC) matrix incorporated by new azo-chromophore compounds that undergo conformational changes under irradiation by light with wavelengths of 365 and 450 nm has been studied. The illumination conditions optimum for controlling the transition from the isotropic to LC phase have been established together with the time required for the UV-induced LC transition to the isotropic phase and the time for which a medium retains its isotropic liquid properties after UV illumination. The feasibility of controlling the localization of CdSe/ZnS quantum dots incorporated into the matrix with azo-chromophore has been demonstrated. A dynamic experiment with displacement of the sample relative to a slit mask has shown the possibility of moving quantum dots along with the isotropic melt front; the temperature optimum for this effect has been determined.

Abstract Image

液晶基质在纳米复合材料光控有序中的功能掺杂
研究了在365 nm和450 nm光照射下,新型偶氮发色团化合物掺入液晶(LC)基质的相行为。建立了控制从各向同性到LC相转变的最佳照明条件,以及UV诱导的LC向各向同性相转变所需的时间和介质在UV照射后保持其各向同性液体性质的时间。证明了用偶氮发色团控制CdSe/ZnS量子点嵌入矩阵的局域化的可行性。通过试样相对于狭缝掩模的位移的动态实验,证明了量子点沿各向同性熔体前沿移动的可能性;达到这种效果的最佳温度已经确定。
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来源期刊
Nanotechnologies in Russia
Nanotechnologies in Russia NANOSCIENCE & NANOTECHNOLOGY-
CiteScore
1.20
自引率
0.00%
发文量
0
期刊介绍: Nanobiotechnology Reports publishes interdisciplinary research articles on fundamental aspects of the structure and properties of nanoscale objects and nanomaterials, polymeric and bioorganic molecules, and supramolecular and biohybrid complexes, as well as articles that discuss technologies for their preparation and processing, and practical implementation of products, devices, and nature-like systems based on them. The journal publishes original articles and reviews that meet the highest scientific quality standards in the following areas of science and technology studies: self-organizing structures and nanoassemblies; nanostructures, including nanotubes; functional and structural nanomaterials; polymeric, bioorganic, and hybrid nanomaterials; devices and products based on nanomaterials and nanotechnology; nanobiology and genetics, and omics technologies; nanobiomedicine and nanopharmaceutics; nanoelectronics and neuromorphic computing systems; neurocognitive systems and technologies; nanophotonics; natural science methods in a study of cultural heritage items; metrology, standardization, and monitoring in nanotechnology.
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