Investigation of the Mechanical and Thermal Properties of MWCNT/SiC-Filled Ethylene–Butene–Terpolymer Rubber

IF 2.4 4区 材料科学 Q2 CRYSTALLOGRAPHY
Crystals Pub Date : 2025-06-05 DOI:10.3390/cryst15060539
Li Zhang, Jianming Liu, Duanjiao Li, Wenxing Sun, Zhi Li, Yongchao Liang, Qiang Fu, Nian Tang, Jie Zhang, Fei Huang, Xuelian Fan, Pengxiang Bai, Haijun Yu, Zhaomeng Liu, Simin Zhu, Dan Qiao
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引用次数: 2

Abstract

Rubber is widely used in daily lives, such as in automobile tires, conveyor belts, sealing rings, and gaskets. The performance of rubber determines its service life. Therefore, it is of crucial importance to improve the performance of rubber. Theoretical studies have found that the inherent properties of nanofillers themselves, the interfacial bonding force between fillers and the matrix, and the uniform dispersibility of nanofillers in the polymer matrix are the most significant factors for enhancing the performance of rubber nanocomposites. This study systematically investigated the synergistic enhancement effect of silicon carbide (SiC) and multi-walled carbon nanotubes (MWCNTs) on the mechanical and thermal properties of ethylene–butene–terpolymer (EBT) composites. By optimizing the addition amount of fillers and improving the interfacial bonding between fillers and the matrix, the influence of filler content on the properties of composites was studied. The results demonstrate that the addition of SiC and MWCNTs significantly improved the storage modulus, tensile strength, hardness, and thermal stability of the composites. In terms of mechanical properties, the tensile strength of the composites increased from 6.68 MPa of pure EBT to 8.46 MPa, and the 100% modulus increased from 2.14 MPa to 3.81 MPa. Moreover, hardness was significantly enhanced under the reinforcement of SiC/CNT fillers. In terms of thermal stability, the composites exhibited excellent resistance to deformation at high temperatures. Through the analysis of the mechanical and thermal properties of the composites, the synergistic enhancement mechanism between SiC and MWCNTs was revealed. The research results provide a theoretical basis for the design and engineering applications of high-performance ethylene–butylene rubber composites.
MWCNT/ sic填充乙烯-丁烯-三元共聚物橡胶的力学和热性能研究
橡胶在日常生活中应用广泛,如汽车轮胎、传送带、密封圈、垫片等。橡胶的性能决定了它的使用寿命。因此,提高橡胶的性能是至关重要的。理论研究发现,纳米填料本身的固有性质、填料与基体之间的界面结合力以及纳米填料在聚合物基体中的均匀分散性是提高橡胶纳米复合材料性能的最重要因素。本研究系统地研究了碳化硅(SiC)和多壁碳纳米管(MWCNTs)对乙烯-丁烯-三元共聚物(EBT)复合材料力学性能和热性能的协同增强效应。通过优化填料的添加量,改善填料与基体的界面结合,研究了填料含量对复合材料性能的影响。结果表明,SiC和MWCNTs的加入显著提高了复合材料的存储模量、抗拉强度、硬度和热稳定性。力学性能方面,复合材料的抗拉强度由纯EBT的6.68 MPa提高到8.46 MPa, 100%模量由2.14 MPa提高到3.81 MPa。此外,在SiC/CNT填料的强化下,硬度显著提高。在热稳定性方面,复合材料在高温下表现出优异的抗变形能力。通过对复合材料力学性能和热性能的分析,揭示了SiC与MWCNTs的协同增强机理。研究结果为高性能乙烯-丁烯橡胶复合材料的设计和工程应用提供了理论依据。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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来源期刊
Crystals
Crystals CRYSTALLOGRAPHYMATERIALS SCIENCE, MULTIDIS-MATERIALS SCIENCE, MULTIDISCIPLINARY
CiteScore
4.20
自引率
11.10%
发文量
1527
审稿时长
16.12 days
期刊介绍: Crystals (ISSN 2073-4352) is an open access journal that covers all aspects of crystalline material research. Crystals can act as a reference, and as a publication resource, to the community. It publishes reviews, regular research articles, and short communications. Our aim is to encourage scientists to publish their experimental and theoretical results in as much detail as possible. Therefore, there is no restriction on article length. Full experimental details must be provided to enable the results to be reproduced. Crystals provides a  forum for the advancement of our understanding of the nucleation, growth, processing, and characterization of crystalline materials. Their mechanical, chemical, electronic, magnetic, and optical properties, and their diverse applications, are all considered to be of importance.
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