N. I. Shishlina, O. G. Zanina, S. V. Shigeev, D. Yu. Svetlolobov, A. N. Prikhodko, O. V. Kuznetsova, N. G. Alfonso
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引用次数: 0
Abstract
The study of the residue of a smoking pipe known as gaans (or “gansa”) dating to the early 20th century from the collection of the State Museum of Oriental Art provided an opportunity to identify the components of ‘smoking tobacco’ used in that period. The analysis of plant microfossils of the residue and comparative analysis with the shoot system of modern plants showed that tobacco was the main component of the smoking blend which also included poppy seed pods and wormwood leaves. The chemical and toxicological analysis using liquid chromatography coupled with quadrupole time-of-flight mass spectrometry (HPLC-QTOF-MS) identified alkaloids and metabolites (nicotine, nicotine-N-oxide, and nornicotine) contained in tobacco leaves and stems. Our analysis confirmed the presence of tobacco phytoliths in the analyzed smoking blend. The nitrogen and carbon isotopic compositions of the organic residue suggest that psychoactive plants such as wormwood which has a high isotopic ratio of nitrogen (δ15N) were mixed with the tobacco. The analysis showed that an anonymous smoker who lived in the early twentieth century blended tobacco and poppy seed pods with wormwood leaves to give it specific flavor and aroma. This blend catered to individual palates and preferences of the smoker or probably reflected cultural traditions of this individual. The study is important because it verified data obtained using three different methods.
对被称为gaans(或“gansa”)的烟管残留物的研究可以追溯到20世纪初,该烟管来自国家东方艺术博物馆的收藏,为鉴定那个时期使用的“吸烟烟草”的成分提供了机会。残留植物微化石分析及与现代植物茎系对比分析表明,烟叶是烟熏混合物的主要成分,还包括罂粟籽荚和艾叶。采用液相色谱联用四极杆飞行时间质谱(HPLC-QTOF-MS)对烟叶和茎中的生物碱和代谢物(尼古丁、尼古丁- n -氧化物和去甲尼古丁)进行了化学和毒理学分析。我们的分析证实在分析的吸烟混合物中存在烟草植物岩。有机残留物的氮、碳同位素组成表明,烟叶中混入了具有高氮同位素比(δ15N)的艾草等具有精神活性的植物。分析表明,一位生活在20世纪初的匿名吸烟者将烟草和罂粟籽荚与苦艾叶混合在一起,使其具有特定的风味和香气。这种混合物迎合了吸烟者的个人口味和偏好,或者可能反映了这个人的文化传统。这项研究很重要,因为它验证了使用三种不同方法获得的数据。
期刊介绍:
Nanobiotechnology Reports publishes interdisciplinary research articles on fundamental aspects of the structure and properties of nanoscale objects and nanomaterials, polymeric and bioorganic molecules, and supramolecular and biohybrid complexes, as well as articles that discuss technologies for their preparation and processing, and practical implementation of products, devices, and nature-like systems based on them. The journal publishes original articles and reviews that meet the highest scientific quality standards in the following areas of science and technology studies: self-organizing structures and nanoassemblies; nanostructures, including nanotubes; functional and structural nanomaterials; polymeric, bioorganic, and hybrid nanomaterials; devices and products based on nanomaterials and nanotechnology; nanobiology and genetics, and omics technologies; nanobiomedicine and nanopharmaceutics; nanoelectronics and neuromorphic computing systems; neurocognitive systems and technologies; nanophotonics; natural science methods in a study of cultural heritage items; metrology, standardization, and monitoring in nanotechnology.