Comparative study of gangue fine aggregate strengthening technologies: microbially induced mineralization, water glass strengthening, and composite strengthening

Chunhua Feng, Linpeng Pan, Ning Li, Yu Chen, Xiaomeng Zhao, Fang Liu, Jianping Zhu, Mingxing Du
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Abstract

When gangue is applied to cementitious materials as fine aggregate, the defects of coal gangue fine aggregate (CFA), such as large porosity, high water absorption, and high surface tension, lead to poor mechanical properties of cementitious materials, which limits its large-scale application in the construction field. In this paper, CFA was strengthened using water glass strengthening, microbial-induced mineralization strengthening, and composite strengthening methods, and the effects of the three strengthening methods on the basic properties of CFA, the mechanical properties of mortar, and the interfacial transition zone (ITZ) were explored. The strengthening mechanism was investigated via X-ray diffraction (XRD), scanning electron microscope (SEM), nanoindentation, and other testing methods. The three strengthening methods were evaluated based on the basic principles of life cycle assessment (LCA). Microbial-induced mineralization can utilize the biological activity of bacteria to achieve targeted repair of the tiny pores of aggregates. Water glass strengthening fills CFA pores and coats the CFA surface with a substance such as a gel produced by the water glass. A composite strengthening treatment can utilize the synergistic reinforcement effect of two single treatments to improve the basic properties of the aggregate. The apparent density of the reinforced CFA increased by 7.69%, the water absorption decreased by 13.07%, and the crushing index decreased by 73.67%. The 3 d compressive strength of the cement mortar prepared with CFA reinforced with composites increased by 44.58%, the 28 d compressive strength increased by 15.43%, and the width of the mortar ITZ decreased from 60 to 30 µm. Water glass strengthening has a smaller environmental impact than microbial strengthening does composite strengthening, and composite strengthening produces an environmental impact that is the sum of the two single strengthening methods.

Graphical abstract

脉石细骨料微生物矿化强化、水玻璃强化、复合强化技术对比研究
煤矸石作为细骨料应用于胶凝材料时,煤矸石细骨料(CFA)孔隙率大、吸水率高、表面张力大等缺陷导致胶凝材料力学性能差,限制了其在建筑领域的大规模应用。本文采用水玻璃强化法、微生物矿化强化法和复合强化法对CFA进行了强化,探讨了三种强化方法对CFA基本性能、砂浆力学性能和界面过渡区(ITZ)的影响。通过x射线衍射(XRD)、扫描电镜(SEM)、纳米压痕等测试方法研究了强化机理。基于生命周期评价(LCA)的基本原理,对三种加固方法进行了评价。微生物诱导矿化可以利用细菌的生物活性对聚集体的微孔进行针对性修复。水玻璃增强填充CFA孔隙,并用水玻璃产生的凝胶等物质覆盖CFA表面。复合加固处理可以利用两种单一处理的协同加固效果来改善骨料的基本性能。增强后的CFA表观密度提高了7.69%,吸水率降低了13.07%,破碎指数降低了73.67%。复合材料增强CFA砂浆的3d抗压强度提高了44.58%,28 d抗压强度提高了15.43%,砂浆ITZ宽度从60µm减小到30µm。水玻璃强化对环境的影响小于微生物强化对复合强化的影响,复合强化产生的环境影响是两种单一强化方法的总和。图形抽象
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