Cerium(IV)-mediated nitrooxylation-phosphorylation of α-(trifluoromethyl)styrenes with H-phosphonates and H-phosphine oxides

IF 2.1 3区化学 Q2 CHEMISTRY, ORGANIC

Tetrahedron Pub Date : 2026-04-01 Epub Date: 2025-12-14 DOI:10.1016/j.tet.2025.135093

Xuxue Zhang , Jiekun Zhu , Junfeng Teng , Chao Zhou , Hao Xu , Xiaolu Yin , Chenxi Li , Xiaoyi Jiang , Song Cao

引用次数: 0

Abstract

An efficient CAN-mediated nitrooxylation-phosphorylation of α-(trifluoromethyl)styrenes with H-phosphonates and H-phosphine oxides was described. This novel difunctionalization reaction could enable the rapid incorporation of nitrooxy group and phosphoryl group into α-(trifluoromethyl)styrene in one step, affording the β-nitrooxy-β-trifluoromethyl-phosphonates and β-nitrooxy-β-trifluoromethyl-phosphine oxides in moderate to good yields.

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铈（IV）介导的α-（三氟甲基）苯乙烯与h -膦酸盐和h -膦氧化物的硝基氧化磷酸化反应

描述了一种高效的can介导的α-（三氟甲基）苯乙烯与h -膦酸盐和h -膦氧化物的硝基氧化磷酸化反应。这种新型的双官能化反应可使硝基和磷基在一步内快速结合到α-（三氟甲基）苯乙烯中，从而得到中高收率的β-硝基氧基-β-三氟甲基膦酸盐和β-硝基氧基-β-三氟甲基膦氧化物。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Tetrahedron 化学-有机化学

CiteScore

3.90

自引率

4.80%

发文量

439

审稿时长

34 days

期刊介绍： Tetrahedron publishes full accounts of research having outstanding significance in the broad field of organic chemistry and its related disciplines, such as organic materials and bio-organic chemistry. Regular papers in Tetrahedron are expected to represent detailed accounts of an original study having substantially greater scope and details than that found in a communication, as published in Tetrahedron Letters. Tetrahedron also publishes thematic collections of papers as special issues and ''Reports'', commissioned in-depth reviews providing a comprehensive overview of a research area.