Biomass pyrolysis to produce hydrogen, methane, carbon monoxide, carbon dioxide, oil and char: a review

IF 25.2 2区 环境科学与生态学 Q1 CHEMISTRY, MULTIDISCIPLINARY
Mira Abou Rjeily, Cédric Gennequin, Jaona Harifidy Randrianalisoa
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引用次数: 0

Abstract

Carbon neutral energies and fine chemicals are urgently needed in the context of the accelerating global warming and associated extreme weather events. Here we review the conversion of biomass into fuels and chemical compounds with focus on biomass properties, mechanisms of biomass thermal decomposition, bio-oil composition and generation, reactor types, pyrolytic classifications, pyrolysis of pure biomass components, and pyrolysis of wood. The main biomass components, namely cellulose, hemicellulose and lignin, are determined by the Van Soest protocol. Biomass decomposition can be explained by the one-step global mechanism, independent competitive or parallel reactions, the multi-component mechanism, the Broido-Shafizadeh scheme, the secondary tar cracking model and the Ranzi scheme. Pyrolysis can be classified into slow, intermediate, fast, and flash pyrolysis. Reactors comprise fixed bed-, fluidized bed- and multistage reactors.

Abstract Image

生物质热解制氢、甲烷、一氧化碳、二氧化碳、油和炭的研究进展
在全球变暖加速和相关极端天气事件的背景下,迫切需要碳中性能源和精细化学品。本文综述了生物质转化为燃料和化合物的研究进展,重点介绍了生物质特性、生物质热分解机理、生物油组成和生成、反应器类型、热解分类、纯生物质组分热解和木材热解。主要的生物质成分,即纤维素、半纤维素和木质素,由Van Soest协议确定。生物质分解可以由一步全局机制、独立竞争或平行反应、多组分机制、Broido-Shafizadeh方案、二次焦油裂解模型和Ranzi方案来解释。热解可分为慢速热解、中间热解、快速热解和闪速热解。反应器包括固定床、流化床和多级反应器。
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来源期刊
Environmental Chemistry Letters
Environmental Chemistry Letters 环境科学-工程:环境
CiteScore
32.00
自引率
7.00%
发文量
175
审稿时长
2 months
期刊介绍: Environmental Chemistry Letters explores the intersections of geology, chemistry, physics, and biology. Published articles are of paramount importance to the examination of both natural and engineered environments. The journal features original and review articles of exceptional significance, encompassing topics such as the characterization of natural and impacted environments, the behavior, prevention, treatment, and control of mineral, organic, and radioactive pollutants. It also delves into interfacial studies involving diverse media like soil, sediment, water, air, organisms, and food. Additionally, the journal covers green chemistry, environmentally friendly synthetic pathways, alternative fuels, ecotoxicology, risk assessment, environmental processes and modeling, environmental technologies, remediation and control, and environmental analytical chemistry using biomolecular tools and tracers.
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