Advances in Selective Recovery and Resource Utilization of Iron, Manganese and Copper from Acid Mine Drainage

IF 9.3 2区 环境科学与生态学 Q1 ENVIRONMENTAL SCIENCES
Xinyi Liu, Yahui Liu, Xinrui Huang, Xinrui Zhong, Renjie Li, Guo Liu, Bing Liao
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引用次数: 0

Abstract

Purpose of review

Acid mine drainage (AMD), characterized by low pH and high concentrations of dissolved metals, poses serious environmental threats but also offers opportunities for metal resource recovery. However, most existing reviews primarily emphasize prevention and treatment methods, often overlooking the potential for selective recovery and valorization of valuable metals. This review aims to systematically summarize and compare current technologies for the selective recovery and resource utilization of key metals, iron, manganese, and copper, from AMD, emphasizing their mechanisms, efficiencies, and interrelations with metal physicochemical properties.

Recent findings

Recent studies have explored various technologies for the selective separation of heavy metals from AMD, including neutralization precipitation, adsorption, electrochemical processes, membrane separation, and biological treatments. The efficiency and selectivity of these technologies largely depend on metal-specific properties such as ionic radius, solubility product, charge density, and Eh–pH stability. Integrated or sequential treatment systems are increasingly adopted to enhance metal-specific selectivity. Recovered metals have been successfully reused in synthesizing adsorbents and catalysts or as secondary mineral resources in metallurgical operations. Moreover, techno-economic and life-cycle analyses indicate that resource-oriented approaches can simultaneously reduce treatment costs, sludge generation, and environmental impacts.

Summary

This review provides a comprehensive evaluation of current advances in selective metal recovery from AMD, establishing clear links between metal properties, removal mechanisms, and process efficiencies. It also underscores the potential of integrating selective recovery technologies with industrial applications. Future research should focus on smart process integration, the development of low-cost and renewable materials, and the use of digital optimization tools to promote scalable, economically feasible, and sustainable AMD management aligned with circular economy principles.

Graphical Abstract

酸性矿山废水中铁、锰、铜的选择性回收与资源化利用研究进展
酸性矿井水具有低pH和高浓度溶解金属的特点,对环境造成了严重的威胁,但也为金属资源的回收提供了机会。然而,大多数现有的评论主要强调预防和治疗方法,往往忽视了有价金属的选择性回收和增值的潜力。本文系统地总结和比较了AMD中关键金属铁、锰、铜的选择性回收和资源化利用的现有技术,重点介绍了其机理、效率及其与金属理化性质的相互关系。最近的研究已经探索了多种从AMD中选择性分离重金属的技术,包括中和沉淀、吸附、电化学过程、膜分离和生物处理。这些技术的效率和选择性在很大程度上取决于金属的特性,如离子半径、溶解度产物、电荷密度和Eh-pH稳定性。集成或顺序处理系统越来越多地采用,以提高金属特异性的选择性。回收的金属已成功地用于合成吸附剂和催化剂,或在冶金作业中作为二次矿产资源。此外,技术经济和生命周期分析表明,以资源为导向的方法可以同时降低处理成本、污泥产生和环境影响。本文综述了从AMD中选择性回收金属的最新进展,建立了金属性质、去除机制和工艺效率之间的明确联系。它还强调了将选择性回收技术与工业应用相结合的潜力。未来的研究应侧重于智能过程集成、低成本和可再生材料的开发,以及使用数字优化工具来促进可扩展、经济上可行和可持续的AMD管理,与循环经济原则相一致。图形抽象
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来源期刊
Current Pollution Reports
Current Pollution Reports Environmental Science-Water Science and Technology
CiteScore
12.10
自引率
1.40%
发文量
31
期刊介绍: Current Pollution Reports provides in-depth review articles contributed by international experts on the most significant developments in the field of environmental pollution.By presenting clear, insightful, balanced reviews that emphasize recently published papers of major importance, the journal elucidates current and emerging approaches to identification, characterization, treatment, management of pollutants and much more.
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