Detection and quantitative assessment of internal short circuits in lithium-ion battery packs based on differential voltage analysis and mahalanobis distance

IF 2.4 4区 化学 Q4 ELECTROCHEMISTRY
Junkun Zhang , Li Jin , Zhongao Wang , Quanhui Li , Xiaoxue Yan , Ertao Lei , Kai Ma , Chao Lyu
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引用次数: 0

Abstract

Accurate and prompt diagnosis of internal short circuits at an early stage is critical for preventing severe safety incidents and ensuring the reliability and safety of lithium-ion batteries. However, existing early-stage internal short-circuit diagnosis methods often rely heavily on high-precision battery models and large volumes of high-quality labeled training data, limiting their practicality and robustness in real-world applications. To address these limitations, this paper proposes a novel method for early detection and quantitative assessment of internal short circuits in lithium-ion battery packs, based on differential voltage (DV) analysis and Mahalanobis distance. The proposed approach extracts a median DV curve from the sorted terminal voltages of individual cells within a battery pack, which serves as a reference to characterize the normal cell behavior. The Mahalanobis distance between each cell's DV curve and the reference curve is then calculated and compared against a threshold to distinguish short-circuited cells from healthy ones. For the identified faulty cells, the short-circuit current and resistance are estimated by analyzing the differences between charging voltage curves across adjacent cycles, enabling precise quantification of fault severity. Experimental validation is conducted using simulated internal short circuits with varying severities. Results show that the proposed method can accurately detect short-circuited cells when the short-circuit resistance is less than or equal to 300 Ω. The maximum and minimum relative errors of short-circuit resistance estimation are 5.21 % and 1.20 %, respectively, demonstrating the effectiveness and accuracy of the proposed method.
基于差分电压分析和马氏距离的锂离子电池组内部短路检测与定量评估
早期准确、及时地诊断内部短路,对于防止严重安全事故的发生,确保锂离子电池的可靠性和安全性至关重要。然而,现有的早期内部短路诊断方法往往严重依赖于高精度的电池模型和大量高质量的标记训练数据,限制了其在实际应用中的实用性和鲁棒性。为了解决这些限制,本文提出了一种基于差分电压(DV)分析和马氏距离的锂离子电池组内部短路早期检测和定量评估的新方法。该方法从电池组内单个电池的分类终端电压中提取中值DV曲线,作为表征正常电池行为的参考。然后计算每个细胞的DV曲线和参考曲线之间的马氏距离,并将其与区分短路细胞和健康细胞的阈值进行比较。对于已识别的故障电池,通过分析相邻周期充电电压曲线的差异来估计短路电流和电阻,从而精确量化故障严重程度。用不同严重程度的模拟内部短路进行了实验验证。结果表明,当短路电阻小于或等于300 Ω时,所提出的方法可以准确地检测出短路电池。短路电阻估计的最大和最小相对误差分别为5.21 %和1.20 %,证明了所提出方法的有效性和准确性。
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来源期刊
CiteScore
3.00
自引率
20.00%
发文量
714
审稿时长
2.6 months
期刊介绍: International Journal of Electrochemical Science is a peer-reviewed, open access journal that publishes original research articles, short communications as well as review articles in all areas of electrochemistry: Scope - Theoretical and Computational Electrochemistry - Processes on Electrodes - Electroanalytical Chemistry and Sensor Science - Corrosion - Electrochemical Energy Conversion and Storage - Electrochemical Engineering - Coatings - Electrochemical Synthesis - Bioelectrochemistry - Molecular Electrochemistry
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