Phase-Change Grating Multispectral Camouflage System for Security Applications: Dynamic Regulation and Information Encryption

IF 10 1区 物理与天体物理 Q1 OPTICS
Zhe Li, Liuxiang Huo, Xiaoyun Ye, Kai Jiang, Liangqing Zhu, Yawei Li, Liyan Shang, Jinzhong Zhang, Zhigao Hu
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To address these challenges, a laser-programmable Ge<sub>2</sub>Sb<sub>2</sub>Te<sub>5</sub> <span data-altimg=\"/cms/asset/ce700898-1486-49ba-b6fe-917bda165524/lpor70518-math-0001.png\"></span><mjx-container ctxtmenu_counter=\"5\" ctxtmenu_oldtabindex=\"1\" jax=\"CHTML\" role=\"application\" sre-explorer- style=\"font-size: 103%; position: relative;\" tabindex=\"0\"><mjx-math aria-hidden=\"true\" location=\"graphic/lpor70518-math-0001.png\"><mjx-semantics><mjx-mrow data-semantic-annotation=\"clearspeak:unit\" data-semantic-children=\"2,5,8\" data-semantic-content=\"9,10\" data-semantic- data-semantic-role=\"implicit\" data-semantic-speech=\"upper G e 2 upper S b 2 upper T e 5\" data-semantic-type=\"infixop\"><mjx-msub data-semantic-children=\"0,1\" data-semantic- data-semantic-parent=\"11\" data-semantic-role=\"unknown\" data-semantic-type=\"subscript\"><mjx-mi data-semantic-font=\"normal\" data-semantic- data-semantic-parent=\"2\" data-semantic-role=\"unknown\" data-semantic-type=\"identifier\"><mjx-c></mjx-c><mjx-c></mjx-c></mjx-mi><mjx-script style=\"vertical-align: -0.15em;\"><mjx-mn data-semantic-annotation=\"clearspeak:simple\" data-semantic-font=\"normal\" data-semantic- data-semantic-parent=\"2\" data-semantic-role=\"integer\" data-semantic-type=\"number\" size=\"s\"><mjx-c></mjx-c></mjx-mn></mjx-script></mjx-msub><mjx-mo data-semantic-added=\"true\" data-semantic- data-semantic-operator=\"infixop,⁢\" data-semantic-parent=\"11\" data-semantic-role=\"multiplication\" data-semantic-type=\"operator\" style=\"margin-left: 0.056em; margin-right: 0.056em;\"><mjx-c></mjx-c></mjx-mo><mjx-msub data-semantic-children=\"3,4\" data-semantic- data-semantic-parent=\"11\" data-semantic-role=\"unknown\" data-semantic-type=\"subscript\"><mjx-mi data-semantic-font=\"normal\" data-semantic- data-semantic-parent=\"5\" data-semantic-role=\"unknown\" data-semantic-type=\"identifier\"><mjx-c></mjx-c><mjx-c></mjx-c></mjx-mi><mjx-script style=\"vertical-align: -0.15em;\"><mjx-mn data-semantic-annotation=\"clearspeak:simple\" data-semantic-font=\"normal\" data-semantic- data-semantic-parent=\"5\" data-semantic-role=\"integer\" data-semantic-type=\"number\" size=\"s\"><mjx-c></mjx-c></mjx-mn></mjx-script></mjx-msub><mjx-mo data-semantic-added=\"true\" data-semantic- data-semantic-operator=\"infixop,⁢\" data-semantic-parent=\"11\" data-semantic-role=\"multiplication\" data-semantic-type=\"operator\" style=\"margin-left: 0.056em; margin-right: 0.056em;\"><mjx-c></mjx-c></mjx-mo><mjx-msub data-semantic-children=\"6,7\" data-semantic- data-semantic-parent=\"11\" data-semantic-role=\"unknown\" data-semantic-type=\"subscript\"><mjx-mi data-semantic-font=\"normal\" data-semantic- data-semantic-parent=\"8\" data-semantic-role=\"unknown\" data-semantic-type=\"identifier\"><mjx-c></mjx-c><mjx-c></mjx-c></mjx-mi><mjx-script style=\"vertical-align: -0.15em;\"><mjx-mn data-semantic-annotation=\"clearspeak:simple\" data-semantic-font=\"normal\" data-semantic- data-semantic-parent=\"8\" data-semantic-role=\"integer\" data-semantic-type=\"number\" size=\"s\"><mjx-c></mjx-c></mjx-mn></mjx-script></mjx-msub></mjx-mrow></mjx-semantics></mjx-math><mjx-assistive-mml display=\"inline\" unselectable=\"on\"><math altimg=\"urn:x-wiley:18638880:media:lpor70518:lpor70518-math-0001\" display=\"inline\" location=\"graphic/lpor70518-math-0001.png\" xmlns=\"http://www.w3.org/1998/Math/MathML\"><semantics><mrow data-semantic-=\"\" data-semantic-annotation=\"clearspeak:unit\" data-semantic-children=\"2,5,8\" data-semantic-content=\"9,10\" data-semantic-role=\"implicit\" data-semantic-speech=\"upper G e 2 upper S b 2 upper T e 5\" data-semantic-type=\"infixop\"><msub data-semantic-=\"\" data-semantic-children=\"0,1\" data-semantic-parent=\"11\" data-semantic-role=\"unknown\" data-semantic-type=\"subscript\"><mi data-semantic-=\"\" data-semantic-font=\"normal\" data-semantic-parent=\"2\" data-semantic-role=\"unknown\" data-semantic-type=\"identifier\">Ge</mi><mn data-semantic-=\"\" data-semantic-annotation=\"clearspeak:simple\" data-semantic-font=\"normal\" data-semantic-parent=\"2\" data-semantic-role=\"integer\" data-semantic-type=\"number\">2</mn></msub><mo data-semantic-=\"\" data-semantic-added=\"true\" data-semantic-operator=\"infixop,⁢\" data-semantic-parent=\"11\" data-semantic-role=\"multiplication\" data-semantic-type=\"operator\">⁢</mo><msub data-semantic-=\"\" data-semantic-children=\"3,4\" data-semantic-parent=\"11\" data-semantic-role=\"unknown\" data-semantic-type=\"subscript\"><mi data-semantic-=\"\" data-semantic-font=\"normal\" data-semantic-parent=\"5\" data-semantic-role=\"unknown\" data-semantic-type=\"identifier\">Sb</mi><mn data-semantic-=\"\" data-semantic-annotation=\"clearspeak:simple\" data-semantic-font=\"normal\" data-semantic-parent=\"5\" data-semantic-role=\"integer\" data-semantic-type=\"number\">2</mn></msub><mo data-semantic-=\"\" data-semantic-added=\"true\" data-semantic-operator=\"infixop,⁢\" data-semantic-parent=\"11\" data-semantic-role=\"multiplication\" data-semantic-type=\"operator\">⁢</mo><msub data-semantic-=\"\" data-semantic-children=\"6,7\" data-semantic-parent=\"11\" data-semantic-role=\"unknown\" data-semantic-type=\"subscript\"><mi data-semantic-=\"\" data-semantic-font=\"normal\" data-semantic-parent=\"8\" data-semantic-role=\"unknown\" data-semantic-type=\"identifier\">Te</mi><mn data-semantic-=\"\" data-semantic-annotation=\"clearspeak:simple\" data-semantic-font=\"normal\" data-semantic-parent=\"8\" data-semantic-role=\"integer\" data-semantic-type=\"number\">5</mn></msub></mrow>${\\rm Ge}_{2}{\\rm Sb}_{2}{\\rm Te}_{5}$</annotation></semantics></math></mjx-assistive-mml></mjx-container> (GST)/Ag grating surface capable of dual-band infrared camouflage with suppressed thermal emission is proposed. This design achieves remarkably low emissivity values of 0.12 in the mid-wave infrared (MWIR) and 0.04 in the long-wave infrared (LWIR) bands. Through laser-induced gradient crystallization, continuous emissivity modulation in the LWIR band is demonstrated, enabling dynamic spectral control. By integrating a visible-transparent and infrared-nondestructive (Si<sub>3</sub>N<sub>4</sub> <span data-altimg=\"/cms/asset/9b50fb9d-5285-4bdb-9010-ca81f7e6fcbc/lpor70518-math-0002.png\"></span><mjx-container ctxtmenu_counter=\"6\" ctxtmenu_oldtabindex=\"1\" jax=\"CHTML\" role=\"application\" sre-explorer- style=\"font-size: 103%; position: relative;\" tabindex=\"0\"><mjx-math aria-hidden=\"true\" location=\"graphic/lpor70518-math-0002.png\"><mjx-semantics><mjx-mrow data-semantic-annotation=\"clearspeak:unit\" data-semantic-children=\"2,5\" data-semantic-content=\"6\" data-semantic- data-semantic-role=\"implicit\" data-semantic-speech=\"upper S i 3 normal upper N 4\" data-semantic-type=\"infixop\"><mjx-msub data-semantic-children=\"0,1\" data-semantic- data-semantic-parent=\"7\" data-semantic-role=\"unknown\" data-semantic-type=\"subscript\"><mjx-mi data-semantic-font=\"normal\" data-semantic- data-semantic-parent=\"2\" data-semantic-role=\"unknown\" data-semantic-type=\"identifier\"><mjx-c></mjx-c><mjx-c></mjx-c></mjx-mi><mjx-script style=\"vertical-align: -0.15em;\"><mjx-mn data-semantic-annotation=\"clearspeak:simple\" data-semantic-font=\"normal\" data-semantic- data-semantic-parent=\"2\" data-semantic-role=\"integer\" data-semantic-type=\"number\" size=\"s\"><mjx-c></mjx-c></mjx-mn></mjx-script></mjx-msub><mjx-mo data-semantic-added=\"true\" data-semantic- data-semantic-operator=\"infixop,⁢\" data-semantic-parent=\"7\" data-semantic-role=\"multiplication\" data-semantic-type=\"operator\" style=\"margin-left: 0.056em; margin-right: 0.056em;\"><mjx-c></mjx-c></mjx-mo><mjx-msub data-semantic-children=\"3,4\" data-semantic- data-semantic-parent=\"7\" data-semantic-role=\"latinletter\" data-semantic-type=\"subscript\"><mjx-mi data-semantic-annotation=\"clearspeak:simple\" data-semantic-font=\"normal\" data-semantic- data-semantic-parent=\"5\" data-semantic-role=\"latinletter\" data-semantic-type=\"identifier\"><mjx-c></mjx-c></mjx-mi><mjx-script style=\"vertical-align: -0.15em;\"><mjx-mn data-semantic-annotation=\"clearspeak:simple\" data-semantic-font=\"normal\" data-semantic- data-semantic-parent=\"5\" data-semantic-role=\"integer\" data-semantic-type=\"number\" size=\"s\"><mjx-c></mjx-c></mjx-mn></mjx-script></mjx-msub></mjx-mrow></mjx-semantics></mjx-math><mjx-assistive-mml display=\"inline\" unselectable=\"on\"><math altimg=\"urn:x-wiley:18638880:media:lpor70518:lpor70518-math-0002\" display=\"inline\" location=\"graphic/lpor70518-math-0002.png\" xmlns=\"http://www.w3.org/1998/Math/MathML\"><semantics><mrow data-semantic-=\"\" data-semantic-annotation=\"clearspeak:unit\" data-semantic-children=\"2,5\" data-semantic-content=\"6\" data-semantic-role=\"implicit\" data-semantic-speech=\"upper S i 3 normal upper N 4\" data-semantic-type=\"infixop\"><msub data-semantic-=\"\" data-semantic-children=\"0,1\" data-semantic-parent=\"7\" data-semantic-role=\"unknown\" data-semantic-type=\"subscript\"><mi data-semantic-=\"\" data-semantic-font=\"normal\" data-semantic-parent=\"2\" data-semantic-role=\"unknown\" data-semantic-type=\"identifier\">Si</mi><mn data-semantic-=\"\" data-semantic-annotation=\"clearspeak:simple\" data-semantic-font=\"normal\" data-semantic-parent=\"2\" data-semantic-role=\"integer\" data-semantic-type=\"number\">3</mn></msub><mo data-semantic-=\"\" data-semantic-added=\"true\" data-semantic-operator=\"infixop,⁢\" data-semantic-parent=\"7\" data-semantic-role=\"multiplication\" data-semantic-type=\"operator\">⁢</mo><msub data-semantic-=\"\" data-semantic-children=\"3,4\" data-semantic-parent=\"7\" data-semantic-role=\"latinletter\" data-semantic-type=\"subscript\"><mi data-semantic-=\"\" data-semantic-annotation=\"clearspeak:simple\" data-semantic-font=\"normal\" data-semantic-parent=\"5\" data-semantic-role=\"latinletter\" data-semantic-type=\"identifier\" mathvariant=\"normal\">N</mi><mn data-semantic-=\"\" data-semantic-annotation=\"clearspeak:simple\" data-semantic-font=\"normal\" data-semantic-parent=\"5\" data-semantic-role=\"integer\" data-semantic-type=\"number\">4</mn></msub></mrow>${\\rm Si}_{3}{\\rm N}_{4}$</annotation></semantics></math></mjx-assistive-mml></mjx-container>) coating, multispectral stealth across visible and infrared wavelengths is achieved. The highly symmetric grating architecture ensures polarization insensitivity and angular robustness, maintaining performance over a wide incidence range (0 <span data-altimg=\"/cms/asset/75c07b5f-eef1-4b71-be1d-3b6e48094fc8/lpor70518-math-0003.png\"></span><mjx-container ctxtmenu_counter=\"7\" ctxtmenu_oldtabindex=\"1\" jax=\"CHTML\" role=\"application\" sre-explorer- style=\"font-size: 103%; position: relative;\" tabindex=\"0\"><mjx-math aria-hidden=\"true\" location=\"graphic/lpor70518-math-0003.png\"><mjx-semantics><mjx-msup data-semantic-children=\"0,1\" data-semantic- data-semantic-role=\"unknown\" data-semantic-speech=\"Superscript ring\" data-semantic-type=\"superscript\"><mjx-mrow data-semantic- data-semantic-parent=\"2\" data-semantic-role=\"unknown\" data-semantic-type=\"empty\"></mjx-mrow><mjx-script style=\"vertical-align: 0.363em;\"><mjx-mo data-semantic- data-semantic-parent=\"2\" data-semantic-role=\"multiplication\" data-semantic-type=\"operator\" size=\"s\"><mjx-c></mjx-c></mjx-mo></mjx-script></mjx-msup></mjx-semantics></mjx-math><mjx-assistive-mml display=\"inline\" unselectable=\"on\"><math altimg=\"urn:x-wiley:18638880:media:lpor70518:lpor70518-math-0003\" display=\"inline\" location=\"graphic/lpor70518-math-0003.png\" xmlns=\"http://www.w3.org/1998/Math/MathML\"><semantics><msup data-semantic-=\"\" data-semantic-children=\"0,1\" data-semantic-role=\"unknown\" data-semantic-speech=\"Superscript ring\" data-semantic-type=\"superscript\"><mrow data-semantic-=\"\" data-semantic-parent=\"2\" data-semantic-role=\"unknown\" data-semantic-type=\"empty\"></mrow><mo data-semantic-=\"\" data-semantic-parent=\"2\" data-semantic-role=\"multiplication\" data-semantic-type=\"operator\">∘</mo></msup>$^\\circ$</annotation></semantics></math></mjx-assistive-mml></mjx-container>–60 <span data-altimg=\"/cms/asset/ae49fb18-0407-4bcb-a284-1c8715e0edf4/lpor70518-math-0004.png\"></span><mjx-container ctxtmenu_counter=\"8\" ctxtmenu_oldtabindex=\"1\" jax=\"CHTML\" role=\"application\" sre-explorer- style=\"font-size: 103%; position: relative;\" tabindex=\"0\"><mjx-math aria-hidden=\"true\" location=\"graphic/lpor70518-math-0004.png\"><mjx-semantics><mjx-msup data-semantic-children=\"0,1\" data-semantic- data-semantic-role=\"unknown\" data-semantic-speech=\"Superscript ring\" data-semantic-type=\"superscript\"><mjx-mrow data-semantic- data-semantic-parent=\"2\" data-semantic-role=\"unknown\" data-semantic-type=\"empty\"></mjx-mrow><mjx-script style=\"vertical-align: 0.363em;\"><mjx-mo data-semantic- data-semantic-parent=\"2\" data-semantic-role=\"multiplication\" data-semantic-type=\"operator\" size=\"s\"><mjx-c></mjx-c></mjx-mo></mjx-script></mjx-msup></mjx-semantics></mjx-math><mjx-assistive-mml display=\"inline\" unselectable=\"on\"><math altimg=\"urn:x-wiley:18638880:media:lpor70518:lpor70518-math-0004\" display=\"inline\" location=\"graphic/lpor70518-math-0004.png\" xmlns=\"http://www.w3.org/1998/Math/MathML\"><semantics><msup data-semantic-=\"\" data-semantic-children=\"0,1\" data-semantic-role=\"unknown\" data-semantic-speech=\"Superscript ring\" data-semantic-type=\"superscript\"><mrow data-semantic-=\"\" data-semantic-parent=\"2\" data-semantic-role=\"unknown\" data-semantic-type=\"empty\"></mrow><mo data-semantic-=\"\" data-semantic-parent=\"2\" data-semantic-role=\"multiplication\" data-semantic-type=\"operator\">∘</mo></msup>$^\\circ$</annotation></semantics></math></mjx-assistive-mml></mjx-container>). Furthermore, by integrating laser-written infrared patterns with color layers and utilizing nanoscale grating height variations (<span data-altimg=\"/cms/asset/58a31a06-e4d5-4779-8fac-39c161440255/lpor70518-math-0005.png\"></span><mjx-container ctxtmenu_counter=\"9\" ctxtmenu_oldtabindex=\"1\" jax=\"CHTML\" role=\"application\" sre-explorer- style=\"font-size: 103%; position: relative;\" tabindex=\"0\"><mjx-math aria-hidden=\"true\" location=\"graphic/lpor70518-math-0005.png\"><mjx-semantics><mjx-mrow data-semantic-children=\"1\" data-semantic-content=\"0\" data-semantic- data-semantic-role=\"addition\" data-semantic-speech=\"plus or minus 20\" data-semantic-type=\"prefixop\"><mjx-mo data-semantic- data-semantic-operator=\"prefixop,±\" data-semantic-parent=\"2\" data-semantic-role=\"addition\" data-semantic-type=\"operator\" rspace=\"1\" style=\"margin-left: 0.056em;\"><mjx-c></mjx-c></mjx-mo><mjx-mn data-semantic-annotation=\"clearspeak:simple\" data-semantic-font=\"normal\" data-semantic- data-semantic-parent=\"2\" data-semantic-role=\"integer\" data-semantic-type=\"number\"><mjx-c></mjx-c><mjx-c></mjx-c></mjx-mn></mjx-mrow></mjx-semantics></mjx-math><mjx-assistive-mml display=\"inline\" unselectable=\"on\"><math altimg=\"urn:x-wiley:18638880:media:lpor70518:lpor70518-math-0005\" display=\"inline\" location=\"graphic/lpor70518-math-0005.png\" xmlns=\"http://www.w3.org/1998/Math/MathML\"><semantics><mrow data-semantic-=\"\" data-semantic-children=\"1\" data-semantic-content=\"0\" data-semantic-role=\"addition\" data-semantic-speech=\"plus or minus 20\" data-semantic-type=\"prefixop\"><mo data-semantic-=\"\" data-semantic-operator=\"prefixop,±\" data-semantic-parent=\"2\" data-semantic-role=\"addition\" data-semantic-type=\"operator\">±</mo><mn data-semantic-=\"\" data-semantic-annotation=\"clearspeak:simple\" data-semantic-font=\"normal\" data-semantic-parent=\"2\" data-semantic-role=\"integer\" data-semantic-type=\"number\">20</mn></mrow>$\\pm 20$</annotation></semantics></math></mjx-assistive-mml></mjx-container> nm) combined with crystal structure replication technology, a multilevel information encryption system is achieved. The system achieves information encryption and controllable elimination through infrared-responsive writing and erasing operations, significantly enhancing security performance. The coordinated material and architectural design approach offers a scalable platform with multifunctional capabilities for military camouflage and optical security applications.","PeriodicalId":204,"journal":{"name":"Laser & Photonics Reviews","volume":"114 1","pages":""},"PeriodicalIF":10.0000,"publicationDate":"2025-10-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Laser & Photonics Reviews","FirstCategoryId":"101","ListUrlMain":"https://doi.org/10.1002/lpor.202501651","RegionNum":1,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"OPTICS","Score":null,"Total":0}
引用次数: 0

Abstract

Traditional infrared camouflage materials often suffer from limitations in multispectral compatibility, fixed emissivity, and angular sensitivity, which restrict their effectiveness against advanced detection technologies. To address these challenges, a laser-programmable Ge2Sb2Te5 Ge2Sb2Te5${\rm Ge}_{2}{\rm Sb}_{2}{\rm Te}_{5}$ (GST)/Ag grating surface capable of dual-band infrared camouflage with suppressed thermal emission is proposed. This design achieves remarkably low emissivity values of 0.12 in the mid-wave infrared (MWIR) and 0.04 in the long-wave infrared (LWIR) bands. Through laser-induced gradient crystallization, continuous emissivity modulation in the LWIR band is demonstrated, enabling dynamic spectral control. By integrating a visible-transparent and infrared-nondestructive (Si3N4 Si3N4${\rm Si}_{3}{\rm N}_{4}$) coating, multispectral stealth across visible and infrared wavelengths is achieved. The highly symmetric grating architecture ensures polarization insensitivity and angular robustness, maintaining performance over a wide incidence range (0 $^\circ$–60 $^\circ$). Furthermore, by integrating laser-written infrared patterns with color layers and utilizing nanoscale grating height variations (±20$\pm 20$ nm) combined with crystal structure replication technology, a multilevel information encryption system is achieved. The system achieves information encryption and controllable elimination through infrared-responsive writing and erasing operations, significantly enhancing security performance. The coordinated material and architectural design approach offers a scalable platform with multifunctional capabilities for military camouflage and optical security applications.

Abstract Image

安全应用的相变光栅多光谱伪装系统:动态调节与信息加密
传统的红外伪装材料在多光谱兼容性、固定发射率和角灵敏度等方面存在局限性,制约了其对先进探测技术的有效性。为了解决这些问题,提出了一种激光可编程Ge2Sb2Te5 Ge2 _ Sb2 _ Te5${\rm Ge}_{2}{\rm Sb}_{2}{\rm Te}_{5}$ (GST)/Ag光栅表面,具有抑制热发射的双频红外伪装能力。该设计实现了中波红外(MWIR)和长波红外(LWIR)波段的低发射率值,分别为0.12和0.04。通过激光诱导的梯度结晶,证明了LWIR波段的连续发射率调制,实现了动态光谱控制。通过集成可见光-透明和红外-无损(Si3N4 Si3 × N4${\rm Si}_{3}{\rm N}_{4}$)涂层,实现了可见光和红外波段的多光谱隐身。高度对称的光栅结构确保了偏振不敏感和角度坚固性,在很宽的入射范围内(0°$^\circ$ -60°$^\circ$)都能保持性能。此外,通过将激光写入红外图案与彩色层相结合,利用纳米光栅高度变化(±20$\pm 20$ nm)结合晶体结构复制技术,实现了多级信息加密系统。系统通过红外响应写入和擦除操作实现信息加密和可控消除,显著提高了安全性能。协调的材料和建筑设计方法为军事伪装和光学安全应用提供了一个具有多功能能力的可扩展平台。
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来源期刊
CiteScore
14.20
自引率
5.50%
发文量
314
审稿时长
2 months
期刊介绍: Laser & Photonics Reviews is a reputable journal that publishes high-quality Reviews, original Research Articles, and Perspectives in the field of photonics and optics. It covers both theoretical and experimental aspects, including recent groundbreaking research, specific advancements, and innovative applications. As evidence of its impact and recognition, Laser & Photonics Reviews boasts a remarkable 2022 Impact Factor of 11.0, according to the Journal Citation Reports from Clarivate Analytics (2023). Moreover, it holds impressive rankings in the InCites Journal Citation Reports: in 2021, it was ranked 6th out of 101 in the field of Optics, 15th out of 161 in Applied Physics, and 12th out of 69 in Condensed Matter Physics. The journal uses the ISSN numbers 1863-8880 for print and 1863-8899 for online publications.
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