Rheological and Microstructural Characterization of Novel High-Elasticity Polymer Modifiers in Asphalt Binders.

Abstract

This study investigates the rheological, thermal, and microstructural performance of three novel high-elasticity polymer modifiers (HEMs) incorporated into asphalt binders. The modifiers were evaluated at their recommended dosages using a multi-scale framework combining rotational viscosity, dynamic shear rheometry (frequency sweeps, Cole-Cole plots, Black diagrams, and master curves), bending beam rheometry, differential scanning calorimetry (DSC), fluorescence microscopy (FM), atomic force microscopy (AFM), and Fourier transform infrared spectroscopy (FTIR). Results show that HEM-B achieved the highest values of the superpave rutting parameter (G*/sinδ = 5.07 kPa unaged, 6.73 kPa aged), reflecting increased high-temperature stiffness but also higher viscosity, which may affect workability. HEM-C exhibited the lowest total enthalpy (1.18 W·g^-1) and a glass transition temperature of -7.7 °C, indicating improved thermal stability relative to other binders. HEM-A showed the greatest increase in fluorescent area (+85%) and the largest reduction in fluorescent number (-60%) compared with base asphalt, demonstrating more homogeneous phase dispersion despite higher enthalpy. Comparison with SBS confirmed that the novel HEMs not only meet but exceed conventional performance thresholds while revealing distinct modification mechanisms, dense cross-linking (HEM-B), functionalized thermoplastic compatibility (HEM-C), and epoxy-tackified network formation (HEM-A). These findings establish quantitative correlations between rheology, thermal stability, and microstructure, underscoring the importance of dosage, compatibility, and polymer network architecture. The study provides a mechanistic foundation for optimizing high-elasticity modifiers in asphalt binders and highlights future needs for dosage normalization and long-term aging evaluation.