Synergistic enhancement of hydrogel/aramid composites by dual nanomicelles: high puncture resistance and ultrafast photoinitiated self-healing properties

IF 21.8 2区材料科学 Q1 MATERIALS SCIENCE, COMPOSITES

Advanced Composites and Hybrid Materials Pub Date : 2025-10-16 DOI:10.1007/s42114-025-01473-0

Mingyuan Zhang, Ting-Ting Li, Xiao Han, Sheng Chu, Yabo Sun, Xingteng Zhang, Ching-Wen Lou, Jia-Horng Lin, Chen-Hung Huang

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引用次数: 0

Abstract

To solve the difficult recycling and poor durability of puncture-resistant soft composites, this study proposed a synergistic reinforcement of hydrogel/aramid composites by dual nanomicelle cross-linked networks using Pluronic F127DA, TiN, and TiO₂ nanoparticles. The TiN nanoparticles, a photothermal conversion material, were introduced into the gel system as toughening particles, and then they were synergized with the micellar state of Pluronic F127DA to form the core–shell structure nanomicelles, which provide more crosslink points and form a triple physical crosslink network with TiO₂ NPs. This synergistic reinforcement had a significant effect on the mechanical properties of the gel matrix (302.27 MJ toughness), self-repair ability (100% under near-infrared light for 5 min), and the amazing improvement of the puncture resistance of the composites (276.78 N cone puncture resistance value, 241.98 N knife puncture resistance value). This study provides an important reference for the design of soft composites with both efficient self-healing properties and high puncture resistance.

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双纳米胶束协同增强水凝胶/芳纶复合材料：高抗穿刺性能和超快光引发自愈性能

为了解决耐刺软复合材料回收难、耐久性差的问题，本研究采用Pluronic F127DA、TiN和TiO2纳米颗粒，通过双纳米胶束交联网络对水凝胶/芳纶复合材料进行协同增强。将光热转化材料TiN纳米颗粒作为增韧颗粒引入凝胶体系，与Pluronic F127DA的胶束态协同形成核壳结构纳米胶束，提供更多交联点，与TiO2 NPs形成三重物理交联网络。这种协同增强对凝胶基体的力学性能（302.27 MJ韧性）、自修复能力（近红外光照射5 min下100%）产生了显著的影响，复合材料的抗穿刺性能（276.78 N锥形穿刺阻力值、241.98 N刀穿刺阻力值）有了惊人的提高。该研究为设计具有高效自愈性能和高抗穿刺性能的软质复合材料提供了重要参考。

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来源期刊

Advanced Composites and Hybrid Materials Multiple-

CiteScore

26.00

自引率

21.40%

发文量

185

期刊介绍： Advanced Composites and Hybrid Materials is a leading international journal that promotes interdisciplinary collaboration among materials scientists, engineers, chemists, biologists, and physicists working on composites, including nanocomposites. Our aim is to facilitate rapid scientific communication in this field. The journal publishes high-quality research on various aspects of composite materials, including materials design, surface and interface science/engineering, manufacturing, structure control, property design, device fabrication, and other applications. We also welcome simulation and modeling studies that are relevant to composites. Additionally, papers focusing on the relationship between fillers and the matrix are of particular interest. Our scope includes polymer, metal, and ceramic matrices, with a special emphasis on reviews and meta-analyses related to materials selection. We cover a wide range of topics, including transport properties, strategies for controlling interfaces and composition distribution, bottom-up assembly of nanocomposites, highly porous and high-density composites, electronic structure design, materials synergisms, and thermoelectric materials. Advanced Composites and Hybrid Materials follows a rigorous single-blind peer-review process to ensure the quality and integrity of the published work.