Dual S-scheme heterojunction nanocomposite-driven charge transport for photocatalytic green energy production and environmental implementations—where to go?

IF 21.8 2区 材料科学 Q1 MATERIALS SCIENCE, COMPOSITES
Haitao Ren, Abdelkader Labidi, Zongcheng Miao, Tian Chang, Mohsen Padervand, Eric Lichtfouse, Chuanyi Wang
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Abstract

Dating back to more than one century ago, the photocatalysis process has demonstrated great promise in addressing environmental problems and the energy crisis. Nevertheless, some single or binary composite materials cannot meet the requirements of large-scale implementations owing to their limited photocatalytic efficiencies. Since 2021, dual S-scheme heterojunction-based nanocomposites have been undertaken as highly efficient photoactive materials for green energy production and environmental applications in order to overcome limitations faced in traditional photocatalysts. Herein, state-of-the-art protocols designed for the synthesis of dual S-scheme heterojunctions are described. How the combined three semiconductors in dual S-scheme heterojunctions can benefit from one another to achieve high energy production and efficient oxidative removal of various pollutants is deeply explained. Photocatalytic reaction mechanisms, by paying special attention to the creation of Fermi levels (Ef) and charge carriers transfer between the three semiconductors in dual S-scheme heterojunctions, are discussed. An entire section has been dedicated to some examples of preparation and applications of double S-scheme heterojunction-based nanocomposites for several photocatalytic applications such as soluble pollutants photodegradation, bacteria disinfection, artificial photosynthesis, H2 generation, H2O2 production, CO2 reduction, and ammonia synthesis. Lastly, the current challenges of dual S-scheme heterojunctions are presented and future research directions are presented. To sum up, dual S-scheme heterojunction nanocomposites are promising photocatalytic materials in the pursuit of sustainable energy production and environmental remediation. In the future, dual S-scheme heterojunctions are highly recommended for photoreactors engineering instead of single or binary photocatalysts to drive forward photocatalysis processes for practical green energy production and environmental protection.

双s方案异质结纳米复合材料驱动的光催化绿色能源生产和环境实现的电荷输运-向何处去?
早在一个多世纪以前,光催化工艺就在解决环境问题和能源危机方面显示出巨大的希望。然而,一些单一或二元复合材料由于其有限的光催化效率而无法满足大规模实施的要求。自2021年以来,为了克服传统光催化剂面临的局限性,双s型异质结纳米复合材料作为高效光活性材料被用于绿色能源生产和环境应用。在这里,最先进的协议设计的合成双s方案异质结描述。深入解释了双s方案异质结中结合的三种半导体如何相互受益以实现高能量生产和各种污染物的高效氧化去除。通过特别关注费米能级(Ef)的产生和双s型异质结中三种半导体之间载流子的转移,讨论了光催化反应机理。一整节专门介绍了双s型异质结纳米复合材料的制备和应用实例,用于几种光催化应用,如可溶性污染物的光降解、细菌消毒、人工光合作用、H2生成、H2O2生成、CO2还原和氨合成。最后,提出了双s型异质结目前面临的挑战和未来的研究方向。综上所述,双s型异质结纳米复合材料在追求可持续能源生产和环境修复方面是有前途的光催化材料。在未来的光反应器工程中,双s型异质结将取代单一或二元光催化剂,推动光催化工艺的发展,实现绿色能源生产和环境保护。
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来源期刊
CiteScore
26.00
自引率
21.40%
发文量
185
期刊介绍: Advanced Composites and Hybrid Materials is a leading international journal that promotes interdisciplinary collaboration among materials scientists, engineers, chemists, biologists, and physicists working on composites, including nanocomposites. Our aim is to facilitate rapid scientific communication in this field. The journal publishes high-quality research on various aspects of composite materials, including materials design, surface and interface science/engineering, manufacturing, structure control, property design, device fabrication, and other applications. We also welcome simulation and modeling studies that are relevant to composites. Additionally, papers focusing on the relationship between fillers and the matrix are of particular interest. Our scope includes polymer, metal, and ceramic matrices, with a special emphasis on reviews and meta-analyses related to materials selection. We cover a wide range of topics, including transport properties, strategies for controlling interfaces and composition distribution, bottom-up assembly of nanocomposites, highly porous and high-density composites, electronic structure design, materials synergisms, and thermoelectric materials. Advanced Composites and Hybrid Materials follows a rigorous single-blind peer-review process to ensure the quality and integrity of the published work.
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