{"title":"Evaporation Heat Transfer Characteristics of Fourth-Generation Refrigerants in Nano/Microchannels","authors":"Yawen Ding, Shasha Ma, Shuai Gong","doi":"10.1021/acs.langmuir.5c04010","DOIUrl":null,"url":null,"abstract":"Fourth-generation refrigerants are characterized by their ultralow global warming potential (GWP), negligible ozone depletion potential (ODP), and superior thermophysical properties. These advantages have spurred growing interest in their adoption, with hydrocarbon-based alternatives such as R290 and R600a emerging as particularly promising options. However, the evaporation heat transfer performance of these next-generation refrigerants remains insufficiently explored, particularly in miniaturized thermal management systems. In this paper, we systematically investigate the evaporation heat transfer characteristics of fourth-generation refrigerants in nano- to microscale channels using the contact line heat transfer theory. We compare the heat transfer performances of R290 and R600a with those of R134a, a third-generation refrigerant. The results demonstrate that R290 and R600a are effective ecofriendly alternatives for nano/microchannel evaporation applications. On this as a basis, we designed a micro-nano composite wick evaporator, consisting of a nanochannel membrane for evaporation and an underlying microchannel liquid supply structure. The optimal channel dimensions for maximizing device-level heat flux are determined using R290 and R600a as the working fluids. This study elucidates the evaporation heat transfer mechanisms of fourth-generation refrigerants in nano/microchannels, providing fundamental insights for the design and optimization of nanochannel evaporators.","PeriodicalId":50,"journal":{"name":"Langmuir","volume":"28 1","pages":""},"PeriodicalIF":3.9000,"publicationDate":"2025-10-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Langmuir","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1021/acs.langmuir.5c04010","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
Fourth-generation refrigerants are characterized by their ultralow global warming potential (GWP), negligible ozone depletion potential (ODP), and superior thermophysical properties. These advantages have spurred growing interest in their adoption, with hydrocarbon-based alternatives such as R290 and R600a emerging as particularly promising options. However, the evaporation heat transfer performance of these next-generation refrigerants remains insufficiently explored, particularly in miniaturized thermal management systems. In this paper, we systematically investigate the evaporation heat transfer characteristics of fourth-generation refrigerants in nano- to microscale channels using the contact line heat transfer theory. We compare the heat transfer performances of R290 and R600a with those of R134a, a third-generation refrigerant. The results demonstrate that R290 and R600a are effective ecofriendly alternatives for nano/microchannel evaporation applications. On this as a basis, we designed a micro-nano composite wick evaporator, consisting of a nanochannel membrane for evaporation and an underlying microchannel liquid supply structure. The optimal channel dimensions for maximizing device-level heat flux are determined using R290 and R600a as the working fluids. This study elucidates the evaporation heat transfer mechanisms of fourth-generation refrigerants in nano/microchannels, providing fundamental insights for the design and optimization of nanochannel evaporators.
期刊介绍:
Langmuir is an interdisciplinary journal publishing articles in the following subject categories:
Colloids: surfactants and self-assembly, dispersions, emulsions, foams
Interfaces: adsorption, reactions, films, forces
Biological Interfaces: biocolloids, biomolecular and biomimetic materials
Materials: nano- and mesostructured materials, polymers, gels, liquid crystals
Electrochemistry: interfacial charge transfer, charge transport, electrocatalysis, electrokinetic phenomena, bioelectrochemistry
Devices and Applications: sensors, fluidics, patterning, catalysis, photonic crystals
However, when high-impact, original work is submitted that does not fit within the above categories, decisions to accept or decline such papers will be based on one criteria: What Would Irving Do?
Langmuir ranks #2 in citations out of 136 journals in the category of Physical Chemistry with 113,157 total citations. The journal received an Impact Factor of 4.384*.
This journal is also indexed in the categories of Materials Science (ranked #1) and Multidisciplinary Chemistry (ranked #5).