Production and characterization of epoxy based biocomposites using pectin biopolymer derived from Passiflora edulis husk and areca fibre

IF 4 3区 化学 Q2 POLYMER SCIENCE
R. Ashok Gandhi, V. Jayaseelan, S. Sambath, VijayAnanth Suyamburajan
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引用次数: 0

Abstract

Composites’ many desirable qualities—including low density, high rigidity, light weight, and improved mechanical performance—have prompted much research into composite manufacturing. Because of these qualities, composites have become the material of choice in many other industries, such as the automotive, building, sports, consumer goods, and engineering fields. Reinforcing epoxy-based composites with 30 vol. % areca nut fibre and pectin made from the husks of Passiflora edulis in different volume percentages for filler. In order to enhance interfacial bonding, the fibre and filler were surface modified before production with 3-Aminopropyltrimethoxysilane (3-APTMS), a silane coupling agent. The water absorption, mechanical, fatigue, and creep tests were carried out in compliance with the applicable ASTM standards. According to the results, composite produced with 30 vol. % of fibre and 3 vol.% of pectin outperformed in mechanical properties. Similarly, the same composite demonstrated improved fatigue resistance in terms of life counts. The scanning electron microscopy (SEM) analysis of the failure mechanisms verified the efficient connection between the fibres and the matrix, as well as the uniform distribution of the filler. On the other hand, the RAP2 composite with 5 vol. % filler, showed marginally higher water absorption (4.9%), and the highest hardness up to 92 Shore-D. Moreover the same composite outperformed in creep resistance with a lowest strain rate of 0.0256 at 15,000 s. These positive outcomes by the addition of pectin in the composite may lead high performance applications in automotives, defence, infrastructure and sports.

以西番莲果壳和槟榔纤维为原料的果胶生物聚合物为原料的环氧基生物复合材料的制备和表征
复合材料的许多令人满意的品质——包括低密度、高刚性、重量轻和改进的机械性能——促使了对复合材料制造的大量研究。由于这些品质,复合材料已成为许多其他行业的首选材料,如汽车、建筑、体育、消费品和工程领域。用体积% 30的槟榔纤维和不同体积百分比的西番莲果皮制成的果胶作为填料,增强环氧基复合材料。在生产前,用硅烷偶联剂3-氨丙基三甲氧基硅烷(3-APTMS)对纤维和填料进行表面改性,以增强界面结合。根据适用的ASTM标准进行了吸水、机械、疲劳和蠕变试验。结果表明,纤维质量分数为30%,果胶质量分数为3%的复合材料具有较好的力学性能。同样,相同的复合材料在寿命方面也表现出了更好的抗疲劳性能。扫描电镜(SEM)分析了破坏机理,验证了纤维与基体的有效连接以及填料的均匀分布。另一方面,添加5 vol. %填料的RAP2复合材料的吸水率略高(4.9%),硬度最高可达92 Shore-D。此外,该复合材料的抗蠕变性能也较好,在15000 s时应变率最低,为0.0256。在复合材料中添加果胶的这些积极成果可能会导致汽车、国防、基础设施和体育领域的高性能应用。
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来源期刊
Polymer Bulletin
Polymer Bulletin 化学-高分子科学
CiteScore
6.00
自引率
6.20%
发文量
0
审稿时长
5.5 months
期刊介绍: "Polymer Bulletin" is a comprehensive academic journal on polymer science founded in 1988. It was founded under the initiative of the late Mr. Wang Baoren, a famous Chinese chemist and educator. This journal is co-sponsored by the Chinese Chemical Society, the Institute of Chemistry, and the Chinese Academy of Sciences and is supervised by the China Association for Science and Technology. It is a core journal and is publicly distributed at home and abroad. "Polymer Bulletin" is a monthly magazine with multiple columns, including a project application guide, outlook, review, research papers, highlight reviews, polymer education and teaching, information sharing, interviews, polymer science popularization, etc. The journal is included in the CSCD Chinese Science Citation Database. It serves as the source journal for Chinese scientific and technological paper statistics and the source journal of Peking University's "Overview of Chinese Core Journals."
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