Influence of Ammonium Bisulfate on Anti-corrosion Performance of CoCrNi MEA in Simulated Ammonium Sulfate Mother Liquor

IF 2 4区 材料科学 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY
K. L. Lou, B. Zhang, M. Zhu, Y. F. Yuan, S. Y. Guo
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Abstract

This work investigated the influence of NH4HSO4 concentration on the corrosion behavior of CoCrNi medium-entropy alloy (MEA) in ammonium sulfate mother liquor. The results suggest that the addition of NH4HSO4 decreases the corrosion resistance of the MEA. With increasing NH4HSO4 concentration, the pits generated on the alloy significantly increase. Under the collective destruction caused by H+ ions, H atoms and Cl- ions, the thickness and integrity of passivation film decrease, causing a deterioration in its protective performance. Meanwhile, adding NH4HSO4 significantly alters the electronic structure of surface film, weakens its stability and results in serious damage to the corrosion resistance of the MEA.

Abstract Image

硫酸氢铵对模拟硫酸铵母液中CoCrNi MEA防腐性能的影响
研究了NH4HSO4浓度对CoCrNi中熵合金(MEA)在硫酸铵母液中腐蚀行为的影响。结果表明,NH4HSO4的加入降低了MEA的耐蚀性。随着NH4HSO4浓度的增加,合金表面产生的凹坑数量显著增加。在H+离子、H原子和Cl-离子的集体破坏下,钝化膜的厚度和完整性下降,导致其防护性能下降。同时,NH4HSO4的加入显著改变了表面膜的电子结构,降低了膜的稳定性,对MEA的耐腐蚀性能造成了严重的破坏。
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来源期刊
Journal of Materials Engineering and Performance
Journal of Materials Engineering and Performance 工程技术-材料科学:综合
CiteScore
3.90
自引率
13.00%
发文量
1120
审稿时长
4.9 months
期刊介绍: ASM International''s Journal of Materials Engineering and Performance focuses on solving day-to-day engineering challenges, particularly those involving components for larger systems. The journal presents a clear understanding of relationships between materials selection, processing, applications and performance. The Journal of Materials Engineering covers all aspects of materials selection, design, processing, characterization and evaluation, including how to improve materials properties through processes and process control of casting, forming, heat treating, surface modification and coating, and fabrication. Testing and characterization (including mechanical and physical tests, NDE, metallography, failure analysis, corrosion resistance, chemical analysis, surface characterization, and microanalysis of surfaces, features and fractures), and industrial performance measurement are also covered
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