Recent Advances in Photocatalytic Transformations of Dioxazolones

IF 4 2区化学 Q2 CHEMISTRY, APPLIED

Advanced Synthesis & Catalysis Pub Date : 2025-10-14 DOI:10.1002/adsc.70158

Shaofeng Gong, Sheng‐Hua Wang, Zu‐Li Wang, Wei‐Min He

引用次数: 0

Abstract

As efficient nitrogen radical precursors, dioxazolones have emerged as key intermediates in photocatalytic CN bond construction due to their mild reaction conditions, and generation of only CO2 as a byproduct. This review summarizes recent advances in the application of dioxazolones in photocatalytic nitrene transfer reactions, with a focus on synthetic methodologies for diverse amides and their derivatives and the mechanistic insights into different catalytic systems. The aim is to provide guidance for developing green and efficient CN, SN, PN, and SN bond formation strategies and to promote the application of photocatalytic nitrene transfer reactions in pharmaceutical and materials science.

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二恶唑酮类化合物光催化转化研究进展

作为高效的氮自由基前体，二恶唑酮类化合物因其反应条件温和且仅产生CO2作为副产物而成为光催化C - _ - N键构建的关键中间体。本文综述了近年来二恶唑酮类化合物在光催化亚硝基转移反应中的应用进展，重点介绍了各种酰胺及其衍生物的合成方法以及不同催化体系的机理。旨在为开发绿色高效的C _ _ _ N、S _ _ N、P _ _ N和S _ _ N键形成策略提供指导，并促进光催化亚硝基转移反应在制药和材料科学中的应用。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Advanced Synthesis & Catalysis 化学-应用化学

CiteScore

9.40

自引率

7.40%

发文量

447

审稿时长

1.8 months

期刊介绍： Advanced Synthesis & Catalysis (ASC) is the leading primary journal in organic, organometallic, and applied chemistry. The high impact of ASC can be attributed to the unique focus of the journal, which publishes exciting new results from academic and industrial labs on efficient, practical, and environmentally friendly organic synthesis. While homogeneous, heterogeneous, organic, and enzyme catalysis are key technologies to achieve green synthesis, significant contributions to the same goal by synthesis design, reaction techniques, flow chemistry, and continuous processing, multiphase catalysis, green solvents, catalyst immobilization, and recycling, separation science, and process development are also featured in ASC. The Aims and Scope can be found in the Notice to Authors or on the first page of the table of contents in every issue.