{"title":"Sonochemical Synthesis of Submicrometer Ga-Based Particles for Cu-to-Cu Interconnection","authors":"Tzu-hsuan Huang, , , Che-yu Yeh, , , Chih-han Yang, , , Yu-chen Liu, , and , Shih-kang Lin*, ","doi":"10.1021/acsaelm.5c01346","DOIUrl":null,"url":null,"abstract":"<p >Heterogeneous integration has been the most important electronic packaging technology, with the emerging needs of miniaturization of electronic devices. Conventional solders are gradually unable to meet the requirements of advanced electronic interconnection, e.g., 3D IC and high-power devices, which are operated in extreme conditions. We previously proposed gallium (Ga)-based transient liquid phase bonding for forming face-centered cubic solid-solution joints without the formation of intermetallic compounds, which guarantees thermal stability and reliability. However, a scalable transfer technology and the associated material are required to realize its industrial applications. Herein, we synthesized Ga-based submicrometer particles (SMPs) by a sonochemical process as the filler material for Ga-based paste. With the Ga-based paste, high-strength, thermally stable, and low-resistance Cu-to-Cu bonding is achieved with a relatively low processing temperature and short bonding time. We demonstrated the potential and feasibility of a Ga-based SMP for high-performance Cu-to-Cu bonding.</p>","PeriodicalId":3,"journal":{"name":"ACS Applied Electronic Materials","volume":"7 19","pages":"8969–8977"},"PeriodicalIF":4.7000,"publicationDate":"2025-09-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.acs.org/doi/pdf/10.1021/acsaelm.5c01346","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"ACS Applied Electronic Materials","FirstCategoryId":"88","ListUrlMain":"https://pubs.acs.org/doi/10.1021/acsaelm.5c01346","RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"ENGINEERING, ELECTRICAL & ELECTRONIC","Score":null,"Total":0}
引用次数: 0
Abstract
Heterogeneous integration has been the most important electronic packaging technology, with the emerging needs of miniaturization of electronic devices. Conventional solders are gradually unable to meet the requirements of advanced electronic interconnection, e.g., 3D IC and high-power devices, which are operated in extreme conditions. We previously proposed gallium (Ga)-based transient liquid phase bonding for forming face-centered cubic solid-solution joints without the formation of intermetallic compounds, which guarantees thermal stability and reliability. However, a scalable transfer technology and the associated material are required to realize its industrial applications. Herein, we synthesized Ga-based submicrometer particles (SMPs) by a sonochemical process as the filler material for Ga-based paste. With the Ga-based paste, high-strength, thermally stable, and low-resistance Cu-to-Cu bonding is achieved with a relatively low processing temperature and short bonding time. We demonstrated the potential and feasibility of a Ga-based SMP for high-performance Cu-to-Cu bonding.
期刊介绍:
ACS Applied Electronic Materials is an interdisciplinary journal publishing original research covering all aspects of electronic materials. The journal is devoted to reports of new and original experimental and theoretical research of an applied nature that integrate knowledge in the areas of materials science, engineering, optics, physics, and chemistry into important applications of electronic materials. Sample research topics that span the journal's scope are inorganic, organic, ionic and polymeric materials with properties that include conducting, semiconducting, superconducting, insulating, dielectric, magnetic, optoelectronic, piezoelectric, ferroelectric and thermoelectric.
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