{"title":"Evading the strength and machinability trade-off in AlN-BN/Mo functionally graded material via reacted phases distribution","authors":"Yueqi Wu , Yunzi Li , Mingyong Jia , Qiang Shen , Fei Chen","doi":"10.1016/j.matlet.2025.139588","DOIUrl":null,"url":null,"abstract":"<div><div>AlN/Mo composites are promising for aerospace thermal protection systems but suffer from a critical strength-machinability trade-off. This work presents a novel AlN-BN/Mo functionally graded material (FGM) that successfully resolves this conflict. Fabricated via a gradient sintering strategy using Field-Assisted Sintering Technology (FAST), the FGM exhibits an exceptional synergy of properties, achieving an ultrahigh flexural strength of 971.9 MPa alongside excellent machinability. The material's performance originates from a temperature-induced gradient in its microstructure and phase composition. This graded structure features softer, machinable AlN-BN-rich ends supported by a robust, high-strength Mo-rich core. This core's uniform composite microstructure is the primary source of the material's superior strength, offering an effective pathway for developing reliable high-temperature components.</div></div>","PeriodicalId":384,"journal":{"name":"Materials Letters","volume":"404 ","pages":"Article 139588"},"PeriodicalIF":2.7000,"publicationDate":"2025-09-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Materials Letters","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0167577X25016180","RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
AlN/Mo composites are promising for aerospace thermal protection systems but suffer from a critical strength-machinability trade-off. This work presents a novel AlN-BN/Mo functionally graded material (FGM) that successfully resolves this conflict. Fabricated via a gradient sintering strategy using Field-Assisted Sintering Technology (FAST), the FGM exhibits an exceptional synergy of properties, achieving an ultrahigh flexural strength of 971.9 MPa alongside excellent machinability. The material's performance originates from a temperature-induced gradient in its microstructure and phase composition. This graded structure features softer, machinable AlN-BN-rich ends supported by a robust, high-strength Mo-rich core. This core's uniform composite microstructure is the primary source of the material's superior strength, offering an effective pathway for developing reliable high-temperature components.
期刊介绍:
Materials Letters has an open access mirror journal Materials Letters: X, sharing the same aims and scope, editorial team, submission system and rigorous peer review.
Materials Letters is dedicated to publishing novel, cutting edge reports of broad interest to the materials community. The journal provides a forum for materials scientists and engineers, physicists, and chemists to rapidly communicate on the most important topics in the field of materials.
Contributions include, but are not limited to, a variety of topics such as:
• Materials - Metals and alloys, amorphous solids, ceramics, composites, polymers, semiconductors
• Applications - Structural, opto-electronic, magnetic, medical, MEMS, sensors, smart
• Characterization - Analytical, microscopy, scanning probes, nanoscopic, optical, electrical, magnetic, acoustic, spectroscopic, diffraction
• Novel Materials - Micro and nanostructures (nanowires, nanotubes, nanoparticles), nanocomposites, thin films, superlattices, quantum dots.
• Processing - Crystal growth, thin film processing, sol-gel processing, mechanical processing, assembly, nanocrystalline processing.
• Properties - Mechanical, magnetic, optical, electrical, ferroelectric, thermal, interfacial, transport, thermodynamic
• Synthesis - Quenching, solid state, solidification, solution synthesis, vapor deposition, high pressure, explosive