Nickel oxide/phthalocyanine bilayer films for hole transport in efficient inverted perovskite solar cells

IF 2.7 4区材料科学 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY

Materials Letters Pub Date : 2025-10-10 DOI:10.1016/j.matlet.2025.139646

M.K. Beisembekov, S.K. Tazhibayev, A.Z. Ziyat, A.K. Aimukhanov, G.I. Omarbekova, Y.Z. Oshanov, S.S. Kassymov, A.K. Zeinidenov

引用次数: 0

Abstract

Bilayer hole-transport layer (HTLs) based on phthalocyanine and its metal complexes (MPc) and nickel oxide (NiOх) are promising HTLs for inversed perovskite solar cells (PSCs). The absorption spectra of bilayer HTLs films showed that the bands broadened in the Q- and B-ranges. It was shown that the Urbach energy depend on the central atom of phthalocyanine. The analysis of the impedance spectra of the photocell shows that the NiOx/MPc increases the mobility of the charge carriers. PSCs based on bilayer HTLs are manufactured. It is shown that PSCs with a NiOx layer have a low power conversion efficiency (PCE) of 16.6 %. The maximum efficiency of PSCs up to 18.9 % is achieved with bilayer HTLs based on NiOx/CoPc.

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用于高效倒钙钛矿太阳能电池空穴传输的氧化镍/酞菁双层膜

基于酞菁及其金属配合物（MPc）和氧化镍（nio）的双层空穴传输层（HTLs）是一种很有前途的用于逆钙钛矿太阳能电池（PSCs）的HTLs。双层HTLs薄膜的吸收光谱在Q和b波段展宽。结果表明，乌尔巴赫能依赖于酞菁的中心原子。光电池的阻抗谱分析表明，NiOx/MPc提高了载流子的迁移率。制备了基于双层HTLs的PSCs。结果表明，含NiOx层的PSCs的功率转换效率（PCE）为16.6%。采用基于NiOx/CoPc的双层HTLs， psc的效率最高可达18.9%。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Materials Letters 工程技术-材料科学：综合

CiteScore

5.60

自引率

3.30%

发文量

1948

审稿时长

50 days

期刊介绍： Materials Letters has an open access mirror journal Materials Letters: X, sharing the same aims and scope, editorial team, submission system and rigorous peer review. Materials Letters is dedicated to publishing novel, cutting edge reports of broad interest to the materials community. The journal provides a forum for materials scientists and engineers, physicists, and chemists to rapidly communicate on the most important topics in the field of materials. Contributions include, but are not limited to, a variety of topics such as: • Materials - Metals and alloys, amorphous solids, ceramics, composites, polymers, semiconductors • Applications - Structural, opto-electronic, magnetic, medical, MEMS, sensors, smart • Characterization - Analytical, microscopy, scanning probes, nanoscopic, optical, electrical, magnetic, acoustic, spectroscopic, diffraction • Novel Materials - Micro and nanostructures (nanowires, nanotubes, nanoparticles), nanocomposites, thin films, superlattices, quantum dots. • Processing - Crystal growth, thin film processing, sol-gel processing, mechanical processing, assembly, nanocrystalline processing. • Properties - Mechanical, magnetic, optical, electrical, ferroelectric, thermal, interfacial, transport, thermodynamic • Synthesis - Quenching, solid state, solidification, solution synthesis, vapor deposition, high pressure, explosive