The effect of rapid resistance heating on microstructure and hydrogen embrittlement of ultra-high-strength hot stamping steel

IF 7 2区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY
Yi Liu , Min Zhang , Hongle Li , Xing Zhang , Shaofei Qu , Borja Fernandez Hernandez , Xianhong Han
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Abstract

The rapid resistance heating (RH) method, which is recognized for its time-saving and energy efficiency, shows potential for producing hot stamping ultra-high-strength steels. However, its impact on mechanical properties, particularly hydrogen embrittlement (HE), has not yet been comprehensively investigated. This study reveals that although RH enhances the mechanical properties of steels, it also leads to an increase in HE sensitivity, which can be alleviated through a baking treatment. Compared to conventional furnace heating (FH), RH significantly shorten the heating duration, refines the prior austenite grain (PAG) size, and increases dislocation density. The finer PAG size enhances the variant selectivity during martensitic transformation, while dislocation strengthening contributed to improved strength and ductility. However, RH specimens exhibited more severe hydrogen-induced deterioration in mechanical performance, with fracture surfaces characterized by distinct intergranular fracture even under short-duration hydrogen charging. Then, the baking treatment was proven effective in reducing HE sensitivity by impeding hydrogen transport via dislocation slip to PAG boundaries, thereby mitigating hydrogen-induced boundary decohesion and delaying the onset of intergranular cracking. Furthermore, the weakened variant selectivity of martensite promotes the formation of low-angle PAG boundary segments, which act to hinder crack propagation. These findings provide a faster and more efficient heating method for producing ultra-high-strength steels with improved performance and reduced HE sensitivity.
快速电阻加热对超高强度热冲压钢组织和氢脆的影响
快速电阻加热(RH)方法因其节省时间和能源效率而被公认,显示出生产热冲压超高强度钢的潜力。然而,其对力学性能的影响,特别是氢脆(HE),尚未得到全面的研究。本研究表明,虽然RH提高了钢的力学性能,但它也会导致HE敏感性的增加,这可以通过烘烤处理来缓解。与传统炉内加热(FH)相比,RH显著缩短了加热时间,细化了先前奥氏体晶粒(PAG)尺寸,并增加了位错密度。更细的PAG尺寸增强了马氏体相变的选择性,而位错强化有助于提高强度和塑性。然而,RH试样表现出更严重的氢诱导力学性能恶化,即使在短时间充氢下,断口表面也表现出明显的晶间断裂。然后,焙烧处理被证明可以有效地降低HE敏感性,通过阻碍氢通过位错滑移到PAG边界,从而减轻氢引起的边界脱黏和延迟晶间开裂的发生。此外,马氏体的变异选择性减弱,促进了低角度PAG边界段的形成,阻碍了裂纹的扩展。这些发现为生产超高强度钢提供了一种更快、更有效的加热方法,提高了钢的性能,降低了HE灵敏度。
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来源期刊
Materials Science and Engineering: A
Materials Science and Engineering: A 工程技术-材料科学:综合
CiteScore
11.50
自引率
15.60%
发文量
1811
审稿时长
31 days
期刊介绍: Materials Science and Engineering A provides an international medium for the publication of theoretical and experimental studies related to the load-bearing capacity of materials as influenced by their basic properties, processing history, microstructure and operating environment. Appropriate submissions to Materials Science and Engineering A should include scientific and/or engineering factors which affect the microstructure - strength relationships of materials and report the changes to mechanical behavior.
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