Phase structure and energy storage properties of Ba(Mg1/3Nb2/3)O3-modified NaNbO3-Bi(Mg2/3Nb1/3)O3-SrTiO3 ceramics

IF 3.9 3区材料科学 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY

Journal of Materials Science Pub Date : 2025-09-29 DOI:10.1007/s10853-025-11527-9

Zixuan Wang, Zhuo Li, Xin Zhao, Simin Cao, Kairu Chen, Yao Liao, Wenfeng Yue, Dawei Wang

{"title":"Phase structure and energy storage properties of Ba(Mg1/3Nb2/3)O3-modified NaNbO3-Bi(Mg2/3Nb1/3)O3-SrTiO3 ceramics","authors":"Zixuan Wang, Zhuo Li, Xin Zhao, Simin Cao, Kairu Chen, Yao Liao, Wenfeng Yue, Dawei Wang","doi":"10.1007/s10853-025-11527-9","DOIUrl":null,"url":null,"abstract":"<div>Sodium niobate (NaNbO3)-based lead-free ceramics have received great attention in the field of pulse power capacitors due to their relatively high energy density and environmental friendliness. Whereas, the mutual optimization of recoverable energy storage density (Wrec) and efficiency (η) remains a critical challenge that hinders their commercialization progress. In this study, the novel 0.95(0.90NaNbO3-0.10((1-x)Bi(Mg2/3Nb1/3)O3-xBa(Mg1/3Nb2/3)O3))-0.05SrTiO3 (NBiMNST-xBaMN) antiferroelectric energy storage ceramics were designed mainly through increasing the energy barrier between AFE and FE states by diminishing ionic displacements in B-site to optimize the energy storage performance (ESP), and synthesized by high-temperature solid-phase reaction. Promisingly, not only excellent Wrec with 3.895 J/cm3 but also outstanding η of 80.36% were obtained simultaneously in NBiMNST-0.35BaMN ceramics under an electric field of 380 kV/cm. Besides, a remarkable frequency stability (the fluctuation of Wrec < 2% within 1–300 Hz) was also performed. All the aforementioned results collectively validate the NBiMNST-0.35BaMN ceramics as an eminent candidate for high-performance pulsed power capacitors.</div>","PeriodicalId":645,"journal":{"name":"Journal of Materials Science","volume":"60 40","pages":"18744 - 18755"},"PeriodicalIF":3.9000,"publicationDate":"2025-09-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Materials Science","FirstCategoryId":"88","ListUrlMain":"https://link.springer.com/article/10.1007/s10853-025-11527-9","RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}

引用次数: 0

Abstract

Sodium niobate (NaNbO₃)-based lead-free ceramics have received great attention in the field of pulse power capacitors due to their relatively high energy density and environmental friendliness. Whereas, the mutual optimization of recoverable energy storage density (W_rec) and efficiency (η) remains a critical challenge that hinders their commercialization progress. In this study, the novel 0.95(0.90NaNbO₃-0.10((1-x)Bi(Mg_2/3Nb_1/3)O₃-xBa(Mg_1/3Nb_2/3)O₃))-0.05SrTiO₃ (NBiMNST-xBaMN) antiferroelectric energy storage ceramics were designed mainly through increasing the energy barrier between AFE and FE states by diminishing ionic displacements in B-site to optimize the energy storage performance (ESP), and synthesized by high-temperature solid-phase reaction. Promisingly, not only excellent W_rec with 3.895 J/cm³ but also outstanding η of 80.36% were obtained simultaneously in NBiMNST-0.35BaMN ceramics under an electric field of 380 kV/cm. Besides, a remarkable frequency stability (the fluctuation of W_rec < 2% within 1–300 Hz) was also performed. All the aforementioned results collectively validate the NBiMNST-0.35BaMN ceramics as an eminent candidate for high-performance pulsed power capacitors.

查看原文本刊更多论文

Ba(Mg1/3Nb2/3) o3改性NaNbO3-Bi(mg2 / 3nb3 /3)O3-SrTiO3陶瓷的相结构和储能性能

铌酸钠（NaNbO3）基无铅陶瓷由于具有较高的能量密度和环境友好性，在脉冲功率电容器领域受到广泛关注。然而，可回收储能密度（Wrec）和效率（η）的相互优化仍然是阻碍其商业化进程的关键挑战。本研究主要通过减小b位的离子位移来增加AFE和FE态之间的能垒，优化储能性能（ESP），设计了新型的0.95(0.90NaNbO3-0.10((1-x)Bi(mgo / 3nb2 /3)O3- xba (mgo / 3nb2 /3)O3) -0.05SrTiO3 （NBiMNST-xBaMN）反铁电储能陶瓷，并采用高温固相反应合成。在380 kV/cm的电场作用下，nbnm - nst -0.35 bamn陶瓷不仅可以获得3.895 J/cm3的优异Wrec，还可以同时获得80.36%的优异η值。此外，还表现出显著的频率稳定性（在1-300 Hz范围内波动率为wrc <； 2%）。所有上述结果共同验证了NBiMNST-0.35BaMN陶瓷作为高性能脉冲功率电容器的杰出候选者。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

求助全文

约1分钟内获得全文求助全文

来源期刊

Journal of Materials Science 工程技术-材料科学：综合

CiteScore

7.90

自引率

4.40%

发文量

1297

审稿时长

2.4 months

期刊介绍： The Journal of Materials Science publishes reviews, full-length papers, and short Communications recording original research results on, or techniques for studying the relationship between structure, properties, and uses of materials. The subjects are seen from international and interdisciplinary perspectives covering areas including metals, ceramics, glasses, polymers, electrical materials, composite materials, fibers, nanostructured materials, nanocomposites, and biological and biomedical materials. The Journal of Materials Science is now firmly established as the leading source of primary communication for scientists investigating the structure and properties of all engineering materials.