Terpyridine-lanthanide metallo-supramolecular polymers: structural diversity and emerging functional applications

IF 7.4 2区材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY

Science China Materials Pub Date : 2025-08-29 DOI:10.1007/s40843-025-3589-9

Jianke Pan (, ), Zhi Chen (, ), Heng Wang (, ), Xiaopeng Li (, ), Xiujun Yu (, )

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引用次数: 0

Abstract

Terpyridine-lanthanide (tpy-Ln) metallo-supramolecular polymers have garnered significant attention in supramolecular chemistry, coordination chemistry and materials science on account of the rigid structure, tunable electronic properties and strong coordination ability of tpy, as well as the unique electronic configuration and remarkable optical, magnetic properties of lanthanides. Over the past decade, the development of tpy-Ln metallo-supramolecular polymers has experienced rapid growth. This review provides an overview of recent progress in tpy-Ln metallo-polymers, covering both crystalline structures and amorphous forms. We focus on the synthesis of these metallo-polymers, with particular emphasis on their structural diversity and self-assembly strategies. Notably, we highlight their promising applications as luminescent materials, chemical sensors, and magnetic materials. Ultimately, this review aims to inspire further exploration into the rational design and synthesis of functional tpy-Ln metallopolymers with enhanced structural precision and enriched functionality, paving the way for their integration into emerging technological applications.

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三吡啶-镧系金属-超分子聚合物：结构多样性和新兴功能应用

三吡啶-镧系金属超分子聚合物（tpy- ln）由于其刚性结构、可调的电子性质和强的配位能力，以及镧系元素独特的电子构型和优异的光学、磁性能，在超分子化学、配位化学和材料科学中受到了广泛的关注。在过去的十年中，tpy-Ln金属超分子聚合物的发展得到了快速的发展。本文综述了近年来tpy-Ln金属聚合物的研究进展，包括晶体结构和非晶结构。我们专注于这些金属聚合物的合成，特别强调它们的结构多样性和自组装策略。值得注意的是，我们强调了它们在发光材料，化学传感器和磁性材料方面的应用前景。最后，本综述旨在进一步探索合理设计和合成具有更高结构精度和丰富功能的功能性tpy-Ln金属聚合物，为其融入新兴技术应用铺平道路。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Science China Materials Materials Science-General Materials Science

CiteScore

11.40

自引率

7.40%

发文量

949

期刊介绍： Science China Materials (SCM) is a globally peer-reviewed journal that covers all facets of materials science. It is supervised by the Chinese Academy of Sciences and co-sponsored by the Chinese Academy of Sciences and the National Natural Science Foundation of China. The journal is jointly published monthly in both printed and electronic forms by Science China Press and Springer. The aim of SCM is to encourage communication of high-quality, innovative research results at the cutting-edge interface of materials science with chemistry, physics, biology, and engineering. It focuses on breakthroughs from around the world and aims to become a world-leading academic journal for materials science.