Fast kinetics of graphite anodes through interface and bulk engineering: a review

IF 7.4 2区材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY

Science China Materials Pub Date : 2025-09-08 DOI:10.1007/s40843-025-3482-2

Xiangqi Liu (, ), Qitao Shi (, ), Chen Lu (, ), Jiaqi Wang (, ), Junjin Zhang (, ), Cheng Zhang (, ), Zhipeng Wang (, ), Luwen Li (, ), Yanbin Shen (, ), Alicja Bachmatiuk, Ruizhi Yang (, ), Mark H. Rümmeli

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引用次数: 0

Abstract

Owing to their advantages such as high energy density and excellent cycle performance, lithium-ion batteries have occupied a dominant position for many years in the fields of consumer electronics, energy storage, and new energy vehicles. Graphite is the most widely commercialized anode material because of its stable layered structure, excellent electrical conductivity, and cost-effectiveness. However, its inherent limitations, notably its relatively low theoretical specific capacity (372 mAh/g) and sluggish intrinsic ion diffusion kinetics, pose significant challenges to the development of high-energy and power density battery systems. This article briefly introduces the intercalation and failure mechanisms of graphite anode materials, reviews the research progress in the bulk and surface regulation of these materials, and discusses their future development prospects.

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基于界面和本体工程的石墨阳极快速动力学研究进展

锂离子电池由于具有能量密度高、循环性能优异等优势，多年来在消费电子、储能、新能源汽车等领域占据主导地位。石墨因其稳定的层状结构、优异的导电性和成本效益而成为最广泛商业化的阳极材料。然而，其固有的局限性，特别是其相对较低的理论比容量（372 mAh/g）和缓慢的内在离子扩散动力学，给高能量和功率密度电池系统的发展带来了重大挑战。本文简要介绍了石墨负极材料的插层和失效机理，综述了石墨负极材料在体积和表面调控方面的研究进展，并对其未来的发展前景进行了展望。

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来源期刊

Science China Materials Materials Science-General Materials Science

CiteScore

11.40

自引率

7.40%

发文量

949

期刊介绍： Science China Materials (SCM) is a globally peer-reviewed journal that covers all facets of materials science. It is supervised by the Chinese Academy of Sciences and co-sponsored by the Chinese Academy of Sciences and the National Natural Science Foundation of China. The journal is jointly published monthly in both printed and electronic forms by Science China Press and Springer. The aim of SCM is to encourage communication of high-quality, innovative research results at the cutting-edge interface of materials science with chemistry, physics, biology, and engineering. It focuses on breakthroughs from around the world and aims to become a world-leading academic journal for materials science.