{"title":"Creep Response of Hydrate-Bearing Sediments during Gas Replacement: from Strain Deformation to Cementation Morphology Evolution","authors":"Yanghui Li, , , Yunhui Wang, , , Lei Huang*, , , Qianyong Liang, , , Gaowei Hu, , and , Peng Wu*, ","doi":"10.1021/acs.energyfuels.5c04138","DOIUrl":null,"url":null,"abstract":"<p >Understanding the deformation behavior, evolution of pore and cementation structures, and permeability changes of hydrate-bearing sediments (HBSs) during the gas replacement-stress coupling process is crucial for ensuring efficient gas replacement and maintaining structural stability. In this study, multistage creep tests, continuous in situ CT imaging combined with digital rock techniques, and pore network modeling were employed to systematically elucidate the evolution mechanisms of pore structure and fluid flow capacity, as well as hydrate morphology and cementation strengthening. Key findings include: (1) under gradually increasing axial load, HBSs initially exhibit stable deformation. However, once a critical strain threshold is exceeded, accelerated strain leads to strength failure. (2) Significant changes occur in pore structure and hydrate morphology throughout the process. Extensive crushing of hydrate particles at the early stage reduces both porosity and hydrate volume ratio, followed by an interplay of compaction, spalling, and recementation that increases hydrate volume. (3) Under the combined effects of gas replacement and stress, the hydrate cementation structure undergoes a distinct damage-repair process, resulting in a strengthened cementation mechanism. (4) Permeability simulations reveal that permeability dramatically decreases from approximately 95–110 D to about 0.015 D, indicating that enhanced cementation and irreversible deformation severely impede fluid transport. These findings provide a robust framework for improving gas replacement efficiency in hydrate reservoirs and ensuring their mechanical stability.</p>","PeriodicalId":35,"journal":{"name":"Energy & Fuels","volume":"39 40","pages":"19286–19297"},"PeriodicalIF":5.3000,"publicationDate":"2025-09-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Energy & Fuels","FirstCategoryId":"5","ListUrlMain":"https://pubs.acs.org/doi/10.1021/acs.energyfuels.5c04138","RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"ENERGY & FUELS","Score":null,"Total":0}
引用次数: 0
Abstract
Understanding the deformation behavior, evolution of pore and cementation structures, and permeability changes of hydrate-bearing sediments (HBSs) during the gas replacement-stress coupling process is crucial for ensuring efficient gas replacement and maintaining structural stability. In this study, multistage creep tests, continuous in situ CT imaging combined with digital rock techniques, and pore network modeling were employed to systematically elucidate the evolution mechanisms of pore structure and fluid flow capacity, as well as hydrate morphology and cementation strengthening. Key findings include: (1) under gradually increasing axial load, HBSs initially exhibit stable deformation. However, once a critical strain threshold is exceeded, accelerated strain leads to strength failure. (2) Significant changes occur in pore structure and hydrate morphology throughout the process. Extensive crushing of hydrate particles at the early stage reduces both porosity and hydrate volume ratio, followed by an interplay of compaction, spalling, and recementation that increases hydrate volume. (3) Under the combined effects of gas replacement and stress, the hydrate cementation structure undergoes a distinct damage-repair process, resulting in a strengthened cementation mechanism. (4) Permeability simulations reveal that permeability dramatically decreases from approximately 95–110 D to about 0.015 D, indicating that enhanced cementation and irreversible deformation severely impede fluid transport. These findings provide a robust framework for improving gas replacement efficiency in hydrate reservoirs and ensuring their mechanical stability.
期刊介绍:
Energy & Fuels publishes reports of research in the technical area defined by the intersection of the disciplines of chemistry and chemical engineering and the application domain of non-nuclear energy and fuels. This includes research directed at the formation of, exploration for, and production of fossil fuels and biomass; the properties and structure or molecular composition of both raw fuels and refined products; the chemistry involved in the processing and utilization of fuels; fuel cells and their applications; and the analytical and instrumental techniques used in investigations of the foregoing areas.