Synthesis of New Vinyl Steroid Derivatives Using Calcium Carbide

IF 0.8 4区 化学 Q4 CHEMISTRY, MULTIDISCIPLINARY
M. S. Ledovskaya, V. V. Voronin
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引用次数: 0

Abstract

New vinyl derivatives of estriol and diosgenin were synthetized by using the vinylation with calcium carbide-derived acetylene. It was demonstrated that the reaction of estriol proceeds with vinylation of all OH-groups to give the corresponding trivinyl derivative. Both vinylated products were characterized in detail for the first time, including two-dimensional NMR spectroscopy for trivinyl ether of estriol.

Abstract Image

利用电石合成新型乙烯基类固醇衍生物
以电石乙炔为原料,通过乙烯化反应合成了雌三醇和薯蓣皂苷元的乙烯基衍生物。结果表明,雌三醇的所有oh基都发生乙烯化反应,得到相应的三乙烯基衍生物。首次对两种乙烯化产物进行了详细的表征,包括对雌三醇三乙烯醚进行了二维NMR表征。
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来源期刊
CiteScore
1.40
自引率
22.20%
发文量
252
审稿时长
2-4 weeks
期刊介绍: Russian Journal of General Chemistry is a journal that covers many problems that are of general interest to the whole community of chemists. The journal is the successor to Russia’s first chemical journal, Zhurnal Russkogo Khimicheskogo Obshchestva (Journal of the Russian Chemical Society ) founded in 1869 to cover all aspects of chemistry. Now the journal is focused on the interdisciplinary areas of chemistry (organometallics, organometalloids, organoinorganic complexes, mechanochemistry, nanochemistry, etc.), new achievements and long-term results in the field. The journal publishes reviews, current scientific papers, letters to the editor, and discussion papers.
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