Jürgen Brillo, Johanna J. Harpur, Hidekazu Kobatake, Hiroyuki Fukuyama
{"title":"Thermophysical Properties of Al–Ti Binary Liquid Alloys","authors":"Jürgen Brillo, Johanna J. Harpur, Hidekazu Kobatake, Hiroyuki Fukuyama","doi":"10.1007/s10765-025-03651-0","DOIUrl":null,"url":null,"abstract":"<div><p>The present work reviews thermophysical property data such as density, surface tension, normal spectral emissivity, and molar heat capacity for liquid binary Al–Ti alloys measured by electromagnetic levitation (EML). The data are studied as functions of temperature and composition. In EML, forces generated by an inhomogeneous magnetic AC field stably position the specimen against gravity. Melting is achieved by inductive heating. Density (volume) is determined from the droplet’s edge curve in the shadow graph profile. Surface tension is determined from the frequency spectrum of the time-dependent radius. Normal spectral emissivity is determined by a direct radiance method, and the laser modulation calorimetry methods is used for the determination of the molar heat capacity. The results are discussed on the basis of thermodynamic solution models, and the obtained excess properties are compared with each other. A great similarity is hereby found demonstrating the pronounce non-ideality of the Al–Ti system.</p></div>","PeriodicalId":598,"journal":{"name":"International Journal of Thermophysics","volume":"46 12","pages":""},"PeriodicalIF":2.9000,"publicationDate":"2025-10-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s10765-025-03651-0.pdf","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"International Journal of Thermophysics","FirstCategoryId":"5","ListUrlMain":"https://link.springer.com/article/10.1007/s10765-025-03651-0","RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
引用次数: 0
Abstract
The present work reviews thermophysical property data such as density, surface tension, normal spectral emissivity, and molar heat capacity for liquid binary Al–Ti alloys measured by electromagnetic levitation (EML). The data are studied as functions of temperature and composition. In EML, forces generated by an inhomogeneous magnetic AC field stably position the specimen against gravity. Melting is achieved by inductive heating. Density (volume) is determined from the droplet’s edge curve in the shadow graph profile. Surface tension is determined from the frequency spectrum of the time-dependent radius. Normal spectral emissivity is determined by a direct radiance method, and the laser modulation calorimetry methods is used for the determination of the molar heat capacity. The results are discussed on the basis of thermodynamic solution models, and the obtained excess properties are compared with each other. A great similarity is hereby found demonstrating the pronounce non-ideality of the Al–Ti system.
期刊介绍:
International Journal of Thermophysics serves as an international medium for the publication of papers in thermophysics, assisting both generators and users of thermophysical properties data. This distinguished journal publishes both experimental and theoretical papers on thermophysical properties of matter in the liquid, gaseous, and solid states (including soft matter, biofluids, and nano- and bio-materials), on instrumentation and techniques leading to their measurement, and on computer studies of model and related systems. Studies in all ranges of temperature, pressure, wavelength, and other relevant variables are included.