Thermophysical Properties of Al–Ti Binary Liquid Alloys

IF 2.9 4区 工程技术 Q3 CHEMISTRY, PHYSICAL
Jürgen Brillo, Johanna J. Harpur, Hidekazu Kobatake, Hiroyuki Fukuyama
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引用次数: 0

Abstract

The present work reviews thermophysical property data such as density, surface tension, normal spectral emissivity, and molar heat capacity for liquid binary Al–Ti alloys measured by electromagnetic levitation (EML). The data are studied as functions of temperature and composition. In EML, forces generated by an inhomogeneous magnetic AC field stably position the specimen against gravity. Melting is achieved by inductive heating. Density (volume) is determined from the droplet’s edge curve in the shadow graph profile. Surface tension is determined from the frequency spectrum of the time-dependent radius. Normal spectral emissivity is determined by a direct radiance method, and the laser modulation calorimetry methods is used for the determination of the molar heat capacity. The results are discussed on the basis of thermodynamic solution models, and the obtained excess properties are compared with each other. A great similarity is hereby found demonstrating the pronounce non-ideality of the Al–Ti system.

Al-Ti二元液态合金的热物理性质
本文综述了电磁悬浮法测量液态二元Al-Ti合金的密度、表面张力、法向光谱发射率和摩尔热容等热物性数据。研究了这些数据作为温度和成分的函数。在EML中,由不均匀的交流磁场产生的力稳定地使试样不受重力的影响。熔化是通过感应加热实现的。密度(体积)由阴影图形轮廓中的液滴边缘曲线确定。表面张力由随时间变化的半径的频谱决定。法向光谱发射率用直接辐射法测定,摩尔热容用激光调制量热法测定。在热力学溶液模型的基础上对所得结果进行了讨论,并对所得的过量性质进行了比较。由此发现了一个很大的相似性,证明了Al-Ti体系的非理想性。
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来源期刊
CiteScore
4.10
自引率
9.10%
发文量
179
审稿时长
5 months
期刊介绍: International Journal of Thermophysics serves as an international medium for the publication of papers in thermophysics, assisting both generators and users of thermophysical properties data. This distinguished journal publishes both experimental and theoretical papers on thermophysical properties of matter in the liquid, gaseous, and solid states (including soft matter, biofluids, and nano- and bio-materials), on instrumentation and techniques leading to their measurement, and on computer studies of model and related systems. Studies in all ranges of temperature, pressure, wavelength, and other relevant variables are included.
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