Wenrui Tian , Daning Zhang , Lulin Xu , Siyu Wang , Huanmin Yao , Yi Lv , Haifan Li , Haoxiang Zhao , Guanjun Zhang
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引用次数: 0
Abstract
Resin-impregnated paper (RIP) composites are widely used as high-performance insulating materials in DC bushings. However, in cold regions, these bushings are subjected to severe thermal stresses that irreversibly deteriorate their mechanical and electrical properties, thereby threatening the reliable operation of power systems. In this paper, accelerated thermal cycling tests are performed on RIP composite, followed by comprehensive characterization of surface morphology, physicochemical properties, mechanical strength, and electrical performance. Results show that microcracks primarily emerge at the early stages of thermal cycling, leading to mechanical and electrical degradation. In addition, moisture ingress and thermal aging elevate the ionic concentration, leading to higher trap density and dielectric losses, which further compromise insulation performance. Finite element simulation results indicate that degradation typically initiates at the interfaces between resin and paper. Furthermore, a mechanical failure lifetime model and an improved Havriliak-Negami dielectric response method are proposed for the prediction and assessment of the degradation state. By integrates experimental analysis, numerical modeling, and condition assessment, this study not only advances the fundamental understanding of thermal stress induced deterioration, but also provides practical guidance for the design of advanced insulating materials and the reliable operation of power equipment in extreme climates.
期刊介绍:
Polymer Degradation and Stability deals with the degradation reactions and their control which are a major preoccupation of practitioners of the many and diverse aspects of modern polymer technology.
Deteriorative reactions occur during processing, when polymers are subjected to heat, oxygen and mechanical stress, and during the useful life of the materials when oxygen and sunlight are the most important degradative agencies. In more specialised applications, degradation may be induced by high energy radiation, ozone, atmospheric pollutants, mechanical stress, biological action, hydrolysis and many other influences. The mechanisms of these reactions and stabilisation processes must be understood if the technology and application of polymers are to continue to advance. The reporting of investigations of this kind is therefore a major function of this journal.
However there are also new developments in polymer technology in which degradation processes find positive applications. For example, photodegradable plastics are now available, the recycling of polymeric products will become increasingly important, degradation and combustion studies are involved in the definition of the fire hazards which are associated with polymeric materials and the microelectronics industry is vitally dependent upon polymer degradation in the manufacture of its circuitry. Polymer properties may also be improved by processes like curing and grafting, the chemistry of which can be closely related to that which causes physical deterioration in other circumstances.