Degradation behavior of resin-impregnated paper composites in DC bushings under extreme thermal cycling: From mechanisms to lifetime assessment

IF 7.4 2区 化学 Q1 POLYMER SCIENCE
Wenrui Tian , Daning Zhang , Lulin Xu , Siyu Wang , Huanmin Yao , Yi Lv , Haifan Li , Haoxiang Zhao , Guanjun Zhang
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引用次数: 0

Abstract

Resin-impregnated paper (RIP) composites are widely used as high-performance insulating materials in DC bushings. However, in cold regions, these bushings are subjected to severe thermal stresses that irreversibly deteriorate their mechanical and electrical properties, thereby threatening the reliable operation of power systems. In this paper, accelerated thermal cycling tests are performed on RIP composite, followed by comprehensive characterization of surface morphology, physicochemical properties, mechanical strength, and electrical performance. Results show that microcracks primarily emerge at the early stages of thermal cycling, leading to mechanical and electrical degradation. In addition, moisture ingress and thermal aging elevate the ionic concentration, leading to higher trap density and dielectric losses, which further compromise insulation performance. Finite element simulation results indicate that degradation typically initiates at the interfaces between resin and paper. Furthermore, a mechanical failure lifetime model and an improved Havriliak-Negami dielectric response method are proposed for the prediction and assessment of the degradation state. By integrates experimental analysis, numerical modeling, and condition assessment, this study not only advances the fundamental understanding of thermal stress induced deterioration, but also provides practical guidance for the design of advanced insulating materials and the reliable operation of power equipment in extreme climates.
在极端热循环下树脂浸渍纸复合材料在直流套管中的降解行为:从机理到寿命评估
树脂浸渍纸(RIP)复合材料是一种广泛应用于直流套管的高性能绝缘材料。然而,在寒冷地区,这些套管受到严重的热应力,不可逆转地恶化其机械和电气性能,从而威胁到电力系统的可靠运行。本文对RIP复合材料进行了加速热循环试验,并对其表面形貌、理化性能、机械强度和电性能进行了综合表征。结果表明,微裂纹主要出现在热循环初期,导致机械和电气退化。此外,受潮和热老化使离子浓度升高,导致陷阱密度和介电损耗增加,从而进一步影响绝缘性能。有限元模拟结果表明,降解通常始于树脂和纸张之间的界面。在此基础上,提出了一种机械失效寿命模型和改进的Havriliak-Negami介电响应法来预测和评估材料的退化状态。本研究通过实验分析、数值模拟和状态评估相结合,不仅加深了对热应力诱发劣化的基本认识,而且为先进绝缘材料的设计和极端气候条件下电力设备的可靠运行提供了实践指导。
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来源期刊
Polymer Degradation and Stability
Polymer Degradation and Stability 化学-高分子科学
CiteScore
10.10
自引率
10.20%
发文量
325
审稿时长
23 days
期刊介绍: Polymer Degradation and Stability deals with the degradation reactions and their control which are a major preoccupation of practitioners of the many and diverse aspects of modern polymer technology. Deteriorative reactions occur during processing, when polymers are subjected to heat, oxygen and mechanical stress, and during the useful life of the materials when oxygen and sunlight are the most important degradative agencies. In more specialised applications, degradation may be induced by high energy radiation, ozone, atmospheric pollutants, mechanical stress, biological action, hydrolysis and many other influences. The mechanisms of these reactions and stabilisation processes must be understood if the technology and application of polymers are to continue to advance. The reporting of investigations of this kind is therefore a major function of this journal. However there are also new developments in polymer technology in which degradation processes find positive applications. For example, photodegradable plastics are now available, the recycling of polymeric products will become increasingly important, degradation and combustion studies are involved in the definition of the fire hazards which are associated with polymeric materials and the microelectronics industry is vitally dependent upon polymer degradation in the manufacture of its circuitry. Polymer properties may also be improved by processes like curing and grafting, the chemistry of which can be closely related to that which causes physical deterioration in other circumstances.
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