Metal–Organic Frameworks for Per- and Polyfluoroalkyl Substances Treatment in Contaminated Water

IF 8.7 1区化学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY

ACS Materials Letters Pub Date : 2025-08-28 DOI:10.1021/acsmaterialslett.5c00902

Rong-Ran Liang, , , Zhaoyi Liu, , , Joshua Rushlow, , , Jiatong Huo, , , Zongsu Han, , , Yihao Yang, , , Hengyu Lin, , and , Hong-Cai Zhou*,

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引用次数: 0

Abstract

Per- and polyfluoroalkyl substances (PFAS) are synthetic pollutants known for their chemical stability, environmental persistence, and toxicological risks. Their widespread use has led to extensive contamination, particularly in aquatic systems. Conventional treatment methods often face challenges such as high energy consumption and the production of secondary pollutants. Metal–organic frameworks (MOFs), with their high surface areas and tunable structures, have emerged as promising materials for PFAS remediation. This review summarizes recent progress in MOF-based PFAS adsorption and degradation, highlighting key frameworks such as MIL, UiO, and ZIF. Mechanistic insights into adsorption behavior and regeneration capabilities are discussed, along with the catalytic performance of MOF composites and postmodified systems in degradation pathways. The review concludes with design strategies for next-generation MOF materials aimed at efficient, sustainable PFAS removal under realistic conditions.

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金属有机框架处理水污染中的全氟和多氟烷基物质

全氟和多氟烷基物质（PFAS）是合成污染物，以其化学稳定性、环境持久性和毒理学风险而闻名。它们的广泛使用导致了广泛的污染，特别是在水生系统中。传统的处理方法往往面临着高能耗和产生二次污染物等挑战。金属有机骨架（mof）具有高表面积和可调结构，是修复PFAS的重要材料。本文综述了基于mof的PFAS吸附和降解的最新进展，重点介绍了MIL、UiO和ZIF等关键框架。讨论了吸附行为和再生能力的机理见解，以及MOF复合材料和后改性系统在降解途径中的催化性能。本文总结了下一代MOF材料的设计策略，旨在在现实条件下高效、可持续地去除PFAS。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

ACS Materials Letters MATERIALS SCIENCE, MULTIDISCIPLINARY-

CiteScore

14.60

自引率

3.50%

发文量

261

期刊介绍： ACS Materials Letters is a journal that publishes high-quality and urgent papers at the forefront of fundamental and applied research in the field of materials science. It aims to bridge the gap between materials and other disciplines such as chemistry, engineering, and biology. The journal encourages multidisciplinary and innovative research that addresses global challenges. Papers submitted to ACS Materials Letters should clearly demonstrate the need for rapid disclosure of key results. The journal is interested in various areas including the design, synthesis, characterization, and evaluation of emerging materials, understanding the relationships between structure, property, and performance, as well as developing materials for applications in energy, environment, biomedical, electronics, and catalysis. The journal has a 2-year impact factor of 11.4 and is dedicated to publishing transformative materials research with fast processing times. The editors and staff of ACS Materials Letters actively participate in major scientific conferences and engage closely with readers and authors. The journal also maintains an active presence on social media to provide authors with greater visibility.