Fabrication of Organic Solar Cells from Surfactant-Free Aqueous Nanoparticle Dispersions

IF 3.6 4区 工程技术 Q3 ENERGY & FUELS
Karen Fischer, Florian Fichtelmann, Jan Bruder, Jonas Armleder, Holger Röhm, Alexander Colsmann
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引用次数: 0

Abstract

Light-harvesting layers in organic bulk-heterojunction solar cells are commonly fabricated from aromatic or even chlorinated solvents, which are often toxic or otherwise hazardous. In this work, nanoparticle dispersions of a blend of poly(3-hexylthiophene) and [6,6]-phenyl C71-butric acid methyl ester (P3HT:PC71BM) are synthesized in water, omitting any stabilizing surfactants which would remain in the layer and hamper the device performance. To overcome wetting issues and to master the deposition of thin films from aqueous dispersions, co-solvents are employed. The solar cells exhibit power conversion efficiencies of 2.7% and show excellent long-term stability, paving a promising way towards the all-eco-friendly production of organic solar cells in the future.

Abstract Image

无表面活性剂纳米水分散体制备有机太阳能电池
有机体异质结太阳能电池中的光收集层通常由芳香或氯化溶剂制成,这些溶剂通常有毒或有其他危险。在这项工作中,在水中合成了聚(3-己基噻吩)和[6,6]-苯基c71 -丁酸甲酯(P3HT:PC71BM)混合物的纳米颗粒分散体,忽略了任何稳定表面活性剂,这些表面活性剂会留在层中并影响器件性能。为了克服润湿问题并掌握水分散体的薄膜沉积,采用了共溶剂。该太阳能电池的功率转换效率为2.7%,并具有良好的长期稳定性,为未来全生态友好型有机太阳能电池的生产铺平了道路。
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来源期刊
Energy technology
Energy technology ENERGY & FUELS-
CiteScore
7.00
自引率
5.30%
发文量
0
审稿时长
1.3 months
期刊介绍: Energy Technology provides a forum for researchers and engineers from all relevant disciplines concerned with the generation, conversion, storage, and distribution of energy. This new journal shall publish articles covering all technical aspects of energy process engineering from different perspectives, e.g., new concepts of energy generation and conversion; design, operation, control, and optimization of processes for energy generation (e.g., carbon capture) and conversion of energy carriers; improvement of existing processes; combination of single components to systems for energy generation; design of systems for energy storage; production processes of fuels, e.g., hydrogen, electricity, petroleum, biobased fuels; concepts and design of devices for energy distribution.
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