Built-in potential engineering via C60 buffer layer for high-performance CsSnGeI3 QD/CsSnBr3 hybrid perovskite solar cells

Abstract

In this study, we systematically investigated a dual-absorber solar-cell architecture under standard AM 1.5 (1-sun) illumination at 300 K using the SCAPS-1D simulation tool. The device configuration comprised an inorganic perovskite material, CsSnBr₃, as the primary light-absorbing layer, followed by a secondary absorber layer composed of CsGeSnI₃ quantum dots (QDs). The investigation primarily focused on evaluating the influence of a fullerene (C₆₀) interfacial buffer layer on the photovoltaic performance metrics of the device, including overall power conversion efficiency (PCE), fill factor (FF), short-circuit current density (J_SC), and open-circuit voltage (V_OC) within the FTO/TiO₂/CsSnBr₃/CsGeSnI₃ QD/P3HT/Ag device structure. Incorporation of the C₆₀ layer as an electron acceptor enhanced charge-carrier separation by inducing a favorable built-in electric field, which in turn facilitated more efficient charge extraction and transport and led to a marked improvement in power conversion efficiency (PCE). To further elucidate the role of the buffer layer, additional simulations were performed, capacitance-voltage (C–V) study, built-in electric field analyzing, carrier recombination and generation. An optimization study of the C₆₀ layer thickness showed that tuning this interfacial buffer to 300 nm yields a maximum power-conversion efficiency of 20.35 %, indicating the critical influence of layer thickness on device performance.