{"title":"Advanced electrochemical insights and biomedical activities of WO3/TiO2 heterostructures","authors":"Satam Alotibi , Awais Khalid , Wajeehah Shahid , Maria Khizar","doi":"10.1016/j.physb.2025.417838","DOIUrl":null,"url":null,"abstract":"<div><div>This study synthesized WO<sub>3</sub>/TiO<sub>2</sub> nanocomposites using a controlled ex-situ technique. The DPPH method was used to prepare the WO3/TiO2 for antioxidant activity. Our findings showed that the highest Percentage of antioxidant activity of WO<sub>3</sub>/TiO<sub>2</sub> exhibited DPPH inhibition activity values of 61.21 %, 64.56 %, and 64.75 %, respectively, due to the activity of DPPH in scavenging radicals. The observed inhibition zones for <em>E. coli</em> and Klebsiella were 25.64 mm and 24.17 mm. For electrochemical studies, at different current densities (0.8, 1.0, 1.2, and 1.4 A g<sup>−1</sup>), the TiO<sub>2</sub>-WO<sub>3</sub> exhibits the longest discharge time. For specific capacitance, TiO<sub>2</sub>-WO<sub>3</sub> composite shows the maximum capacitance, reaching 80 F g<sup>−1</sup> at 0.8 A g<sup>−1</sup> and holding onto 59.5 F g<sup>−1</sup> at 1.4 A g<sup>−1</sup>. In terms of energy density, TiO<sub>2</sub>-WO<sub>3</sub> composite reached a maximum of 6.4 Wh kg<sup>−1</sup> at 0.8 A g<sup>−1</sup>. This study indicates that WO<sub>3</sub>/TiO<sub>2</sub> nanocomposites hold significant potential for future biomedical and high-performance supercapacitors.</div></div>","PeriodicalId":20116,"journal":{"name":"Physica B-condensed Matter","volume":"717 ","pages":"Article 417838"},"PeriodicalIF":2.8000,"publicationDate":"2025-09-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Physica B-condensed Matter","FirstCategoryId":"101","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S092145262500955X","RegionNum":3,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"PHYSICS, CONDENSED MATTER","Score":null,"Total":0}
引用次数: 0
Abstract
This study synthesized WO3/TiO2 nanocomposites using a controlled ex-situ technique. The DPPH method was used to prepare the WO3/TiO2 for antioxidant activity. Our findings showed that the highest Percentage of antioxidant activity of WO3/TiO2 exhibited DPPH inhibition activity values of 61.21 %, 64.56 %, and 64.75 %, respectively, due to the activity of DPPH in scavenging radicals. The observed inhibition zones for E. coli and Klebsiella were 25.64 mm and 24.17 mm. For electrochemical studies, at different current densities (0.8, 1.0, 1.2, and 1.4 A g−1), the TiO2-WO3 exhibits the longest discharge time. For specific capacitance, TiO2-WO3 composite shows the maximum capacitance, reaching 80 F g−1 at 0.8 A g−1 and holding onto 59.5 F g−1 at 1.4 A g−1. In terms of energy density, TiO2-WO3 composite reached a maximum of 6.4 Wh kg−1 at 0.8 A g−1. This study indicates that WO3/TiO2 nanocomposites hold significant potential for future biomedical and high-performance supercapacitors.
本研究采用可控的非原位技术合成了WO3/TiO2纳米复合材料。采用DPPH法制备了具有抗氧化活性的WO3/TiO2。结果表明,WO3/TiO2的抗氧化活性最高,其DPPH抑制活性值分别为61.21%、64.56%和64.75%,这是由于DPPH对自由基的清除作用。对大肠杆菌和克雷伯菌的抑制区分别为25.64 mm和24.17 mm。在电化学研究中,在不同电流密度(0.8、1.0、1.2和1.4 A g−1)下,TiO2-WO3表现出最长的放电时间。在电容方面,TiO2-WO3复合材料表现出最大的电容,在0.8 A g−1时达到80 F g−1,在1.4 A g−1时保持在59.5 F g−1。在能量密度方面,TiO2-WO3复合材料在0.8 a g−1时最大达到6.4 Wh kg−1。该研究表明,WO3/TiO2纳米复合材料在未来的生物医学和高性能超级电容器中具有重要的潜力。
期刊介绍:
Physica B: Condensed Matter comprises all condensed matter and material physics that involve theoretical, computational and experimental work.
Papers should contain further developments and a proper discussion on the physics of experimental or theoretical results in one of the following areas:
-Magnetism
-Materials physics
-Nanostructures and nanomaterials
-Optics and optical materials
-Quantum materials
-Semiconductors
-Strongly correlated systems
-Superconductivity
-Surfaces and interfaces