Dissolved iron distribution and budget in the Solomon Sea

IF 2.5 3区 地球科学 Q2 CHEMISTRY, MULTIDISCIPLINARY
Géraldine Sarthou , Eva Bucciarelli , Fabien Quéroué , François Lacan , Hélène Planquette , Viet Q. Pham , Maxime Grand , Catherine Pradoux , Martine Rodier , Sophie Bonnet , Gérard Eldin , Sophie Cravatte , Catherine Jeandel , Alexandre Ganachaud
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Abstract

As part of the PANDORA cruise (GEOTRACES GP12), concentrations of dissolved iron (dFe) were measured at 11 stations inside and outside the Solomon Sea, a semi-enclosed sea in the western tropical Pacific, with complex topography and straits, and strong western boundary currents supplying the equatorial current system. These measurements aimed to better assess the various sources of dFe in our study area and the Solomon Sea's potential as a source of dFe for the Equatorial Undercurrent (EUC). A simple box model allows calculating and discussing the fate of the dFe in the different water layers flowing through the Solomon Sea and suggests that the amount of dFe enrichment within the enclosed sea was not significant for the lower thermocline and intermediate waters, indicating that most of the dFe was acquired prior to reaching the Solomon Sea at the entrance and/or that inputs are approximately balanced by scavenging within the basin for these two layers. In contrast, dFe enrichment was significant for the upper thermocline layer and the deep waters, highlighting enrichments from external sources, as well as combination of internal processes, such as scavenging and/or organic complexation. The relative dFe contribution of the Solomon Sea to EUC was 20 %, on average. Other sources might thus provide dFe to the EUC, along the water transport downstream of the Solomon Sea (e.g. Bismarck Sea) or from the northern hemisphere. Diazotrophs such as Trichodesmium might also contribute to the dFe enrichment of the EUC after export and remineralization at depth outside the Solomon Sea.
所罗门海溶解铁的分布与收支
作为潘多拉巡航(GEOTRACES GP12)的一部分,在所罗门海内外的11个站点测量了溶解铁(dFe)的浓度。所罗门海位于热带太平洋西部的半封闭海域,地形复杂,海峡狭窄,有强大的西部边界流提供赤道流系统。这些测量旨在更好地评估我们研究区域中dFe的各种来源,以及所罗门海作为赤道潜流(EUC) dFe来源的潜力。一个简单的箱形模型可以计算和讨论流经所罗门海的不同水层中dFe的命运,并表明封闭海中dFe的富集量对于下温跃层和中间水域来说并不显著,这表明大部分dFe是在进入所罗门海之前获得的,并且/或者这两个水层的输入通过盆地内的清除大致平衡。相反,dFe在上层温跃层和深水中富集显著,突出来自外部来源的富集,以及内部过程的组合,如清除和/或有机络合作用。所罗门海对欧盟的相对铁贡献平均为20%。因此,其他来源可能沿着所罗门海(如俾斯麦海)下游的水运或从北半球向欧盟提供dFe。重氮营养体(如Trichodesmium)也可能有助于出口后的EUC的dFe富集和所罗门海以外深度的再矿化。
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来源期刊
Marine Chemistry
Marine Chemistry 化学-海洋学
CiteScore
6.00
自引率
3.30%
发文量
70
审稿时长
4.5 months
期刊介绍: Marine Chemistry is an international medium for the publication of original studies and occasional reviews in the field of chemistry in the marine environment, with emphasis on the dynamic approach. The journal endeavours to cover all aspects, from chemical processes to theoretical and experimental work, and, by providing a central channel of communication, to speed the flow of information in this relatively new and rapidly expanding discipline.
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