The Direct Photochemical Cross-Esterification of Alcohols via Site-Selective C-H Bromination

IF 4.2 2区化学 Q2 CHEMISTRY, MULTIDISCIPLINARY

Chemical Communications Pub Date : 2025-10-04 DOI:10.1039/d5cc03371c

Atsuya Miyamoto, Hiroyoshi Takamura, Isao Kadota, Kenta Tanaka

引用次数: 0

Abstract

We have developed a direct photochemical cross-esterification of alcohols that proceeds via the in-situ generation of acyl bromides. The C-H bond of a benzyl alcohol is selectively activated by a bromo source under light irradiation, enabling the cross-esterification to afford a variety of functionalized esters.

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通过位置选择性C-H溴化直接光化学交叉酯化醇

我们已经开发了一种直接的光化学交叉酯化醇，通过原位生成酰基溴进行。苄基醇的C-H键在光照射下被溴源选择性激活，使交叉酯化反应产生多种官能化酯。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Chemical Communications 化学-化学综合

CiteScore

8.60

自引率

4.10%

发文量

2705

审稿时长

1.4 months

期刊介绍： ChemComm (Chemical Communications) is renowned as the fastest publisher of articles providing information on new avenues of research, drawn from all the world''s major areas of chemical research.