Determination of stability constants of fluoride complexes of Th(IV) and Al(III) by potentiometry with ion selective electrode

IF 1.6 3区化学 Q3 CHEMISTRY, ANALYTICAL

Journal of Radioanalytical and Nuclear Chemistry Pub Date : 2025-08-28 DOI:10.1007/s10967-025-10338-1

Jiaai Chen, Junxin Liu, Daqian Liu, Min Huang, Taoyuan Xiu, Zhirong Liu

{"title":"Determination of stability constants of fluoride complexes of Th(IV) and Al(III) by potentiometry with ion selective electrode","authors":"Jiaai Chen, Junxin Liu, Daqian Liu, Min Huang, Taoyuan Xiu, Zhirong Liu","doi":"10.1007/s10967-025-10338-1","DOIUrl":null,"url":null,"abstract":"<div>Using a fluoride ion selective electrode and multivariate regression analysis conducted with Matlab or Excel, the stability constants of Th(IV) and Al(III) fluorides were determined at 25 °C and 0.01 mol L−1 (NH4)2SO4 ionic strength. The results indicate that the overall stability constants for hydrogen fluoride complexes were β1 = 621.45 and β2 = 6.34 × 103. For thorium fluoride complexes, they were β1 = 3.59 × 105, β2 = 1.89 × 1010, β3 = 6.58 × 1014, and β4 = 1.42 × 1019, respectively. For aluminum fluoride complexes, they were β1 = 3.27 × 105, β2 = 6.53 × 1010, β3 = 5.16 × 1014, β4 = 5.00 × 1017, and β5 = 2.18 × 1019, respectively.</div>","PeriodicalId":661,"journal":{"name":"Journal of Radioanalytical and Nuclear Chemistry","volume":"334 9","pages":"6387 - 6394"},"PeriodicalIF":1.6000,"publicationDate":"2025-08-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Radioanalytical and Nuclear Chemistry","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1007/s10967-025-10338-1","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, ANALYTICAL","Score":null,"Total":0}

引用次数: 0

Abstract

Using a fluoride ion selective electrode and multivariate regression analysis conducted with Matlab or Excel, the stability constants of Th(IV) and Al(III) fluorides were determined at 25 °C and 0.01 mol L⁻¹ (NH₄)₂SO₄ ionic strength. The results indicate that the overall stability constants for hydrogen fluoride complexes were β₁ = 621.45 and β₂ = 6.34 × 10³. For thorium fluoride complexes, they were β₁ = 3.59 × 10⁵, β₂ = 1.89 × 10¹⁰, β₃ = 6.58 × 10¹⁴, and β₄ = 1.42 × 10¹⁹, respectively. For aluminum fluoride complexes, they were β₁ = 3.27 × 10⁵, β₂ = 6.53 × 10¹⁰, β₃ = 5.16 × 10¹⁴, β₄ = 5.00 × 10¹⁷, and β₅ = 2.18 × 10¹⁹, respectively.

Abstract Image

查看原文本刊更多论文

离子选择电极电位法测定Th（IV）和Al（III）氟配合物的稳定性常数

采用氟离子选择电极，利用Matlab或Excel进行多元回归分析，测定了25℃、0.01 mol L−1 (NH4)2SO4离子强度条件下，Th（IV）和Al（III）氟化物的稳定性常数。结果表明，氟化氢配合物的总稳定常数为β1 = 621.45, β2 = 6.34 × 103。对于氟化钍配合物，β1 = 3.59 × 105, β2 = 1.89 × 1010, β3 = 6.58 × 1014, β4 = 1.42 × 1019。对氟化铝复合物,β1 = 3.27×105,β2 = 6.53×1010,β= 5.16×1014,β4 = 5.00×1017,分别和β5 = 2.18×1019。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

求助全文

约1分钟内获得全文求助全文

来源期刊

Journal of Radioanalytical and Nuclear Chemistry 化学-分析化学

CiteScore

2.80

自引率

18.80%

发文量

504

审稿时长

2.2 months

期刊介绍： An international periodical publishing original papers, letters, review papers and short communications on nuclear chemistry. The subjects covered include: Nuclear chemistry, Radiochemistry, Radiation chemistry, Radiobiological chemistry, Environmental radiochemistry, Production and control of radioisotopes and labelled compounds, Nuclear power plant chemistry, Nuclear fuel chemistry, Radioanalytical chemistry, Radiation detection and measurement, Nuclear instrumentation and automation, etc.