Photocatalytic technology in lignin: from traditional depolymerization to actively light-driven conversion

IF 21.8 2区 材料科学 Q1 MATERIALS SCIENCE, COMPOSITES
Cong Liu, Danhua Zhou, Xiaoxian Zheng, Ludan Shang, Junrui Yang, Jiazhi Zhang, Mingxuan Li, Yanhui Li
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Abstract

Lignin is one of the most abundant renewable biopolymers on Earth. In recent years, substantial progress has been achieved in leveraging lignin’s unique properties, especially in the field of photocatalysis. This paper reviews the research progress on lignin-based materials that have been developed through biopolymer engineering techniques, including stages from depolymerization to photocatalytic applications. The role of lignin as a photocatalyst is emphasized, as well as the challenges faced. The relationship between the fundamental structure and properties of lignin is explored, along with the design strategies that are employed to exploit these characteristics. Our review is organized around three main themes: the latest advancements in lignin cleavage technologies (including photocatalytic cleavage), cutting-edge research in lignin-based photocatalytic systems, and the challenges and design strategies associated with the development of lignin photocatalysis. This work aims to contribute significantly to the advancement of sustainable functional photocatalysts derived from lignin. Ultimately, the goal is to develop environmentally friendly and sustainably scalable functional polymer photocatalysts based on lignin in the future.

Graphical Abstract

木质素的光催化技术:从传统解聚到主动光催化转化
木质素是地球上最丰富的可再生生物聚合物之一。近年来,利用木质素的独特性质,特别是在光催化领域取得了实质性进展。综述了生物聚合物工程技术对木质素基材料的研究进展,包括从解聚到光催化应用的各个阶段。强调了木质素作为光催化剂的作用,以及面临的挑战。探讨了木质素的基本结构和特性之间的关系,以及利用这些特性的设计策略。我们的综述围绕三个主题进行:木质素裂解技术(包括光催化裂解)的最新进展,木质素基光催化系统的前沿研究,以及与木质素光催化发展相关的挑战和设计策略。这项工作旨在为木质素衍生的可持续功能光催化剂的发展做出重大贡献。最终,我们的目标是在未来开发基于木质素的环境友好型和可持续扩展的功能聚合物光催化剂。图形抽象
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来源期刊
CiteScore
26.00
自引率
21.40%
发文量
185
期刊介绍: Advanced Composites and Hybrid Materials is a leading international journal that promotes interdisciplinary collaboration among materials scientists, engineers, chemists, biologists, and physicists working on composites, including nanocomposites. Our aim is to facilitate rapid scientific communication in this field. The journal publishes high-quality research on various aspects of composite materials, including materials design, surface and interface science/engineering, manufacturing, structure control, property design, device fabrication, and other applications. We also welcome simulation and modeling studies that are relevant to composites. Additionally, papers focusing on the relationship between fillers and the matrix are of particular interest. Our scope includes polymer, metal, and ceramic matrices, with a special emphasis on reviews and meta-analyses related to materials selection. We cover a wide range of topics, including transport properties, strategies for controlling interfaces and composition distribution, bottom-up assembly of nanocomposites, highly porous and high-density composites, electronic structure design, materials synergisms, and thermoelectric materials. Advanced Composites and Hybrid Materials follows a rigorous single-blind peer-review process to ensure the quality and integrity of the published work.
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