Design of PV Cells and LEDs Robust to Grid Shadowing Losses in Emission.

IF 3.8
ACS Applied Optical Materials Pub Date : 2025-09-11 eCollection Date: 2025-09-26 DOI:10.1021/acsaom.5c00269
Jasper van Gastel, Pyry Kivisaari, Jani Oksanen, Elias Vlieg, John J Schermer
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引用次数: 0

Abstract

In photovoltaics, it is generally assumed that the emission and absorption efficiency is linearly affected by the grid coverage fraction. Typically, the top grid is therefore optimized to allow maximal light exposure with minimal electrical resistance, while the optical properties of the grid are not treated to the same extent. In this work, we provide a numerical study that shows that as a result of the optical properties of the grid, the light extraction efficiency and resulting emission changes nonlinearly with grid coverage, contrary to the standard approximation. If the grid is optically lossy while light is mostly trapped in the diode, the loss in emission is more than linear and therefore larger than expected based on the standard grid shadowing assumption. However, with an optically reflective grid and a good light extraction scheme, the structure obtains a robustness against losses from grid, leading to a meaningful increase in the light extraction efficiency. This is shown using a simple 300 nm GaAs light-emitting diode (LED) structure the emissive properties of which generalize to a thin-film PV cell. Specifically, it is found that depending on the design of the grid and backside mirror, at 10% grid coverage the light extraction efficiency need only be reduced less than 4% absolute. Conversely, in particularly detrimental cases, at 10% grid coverage the light extraction efficiency is reduced by over 35% absolute.

光伏电池和led抗栅格遮挡损耗的设计。
在光伏发电中,通常认为发射和吸收效率受电网覆盖分数的线性影响。因此,通常情况下,顶部网格被优化为允许最大的光照射和最小的电阻,而网格的光学特性没有被处理到相同的程度。在这项工作中,我们提供了一个数值研究,表明由于网格的光学特性,光提取效率和由此产生的发射随网格覆盖呈非线性变化,这与标准近似相反。如果栅格是光学损耗的,而光大部分被困在二极管中,则发射损失大于线性,因此大于基于标准栅格遮蔽假设的预期。然而,通过光学反射网格和良好的光提取方案,该结构对网格损失具有鲁棒性,从而显着提高了光提取效率。这是用一个简单的300纳米砷化镓发光二极管(LED)结构显示的,其发射特性推广到薄膜PV电池。具体而言,根据网格和后视镜的设计,在10%的网格覆盖率下,光提取效率只需要绝对降低不到4%。相反,在特别不利的情况下,在10%的电网覆盖率下,光提取效率绝对降低了35%以上。
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来源期刊
ACS Applied Optical Materials
ACS Applied Optical Materials 材料科学-光学材料-
CiteScore
1.10
自引率
0.00%
发文量
0
期刊介绍: ACS Applied Optical Materials is an international and interdisciplinary forum to publish original experimental and theoretical including simulation and modeling research in optical materials complementing the ACS Applied Materials portfolio. With a focus on innovative applications ACS Applied Optical Materials also complements and expands the scope of existing ACS publications that focus on fundamental aspects of the interaction between light and matter in materials science including ACS Photonics Macromolecules Journal of Physical Chemistry C ACS Nano and Nano Letters.The scope of ACS Applied Optical Materials includes high quality research of an applied nature that integrates knowledge in materials science chemistry physics optical science and engineering.
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