Twisted bilayer Ice as a new class of hydrogen-bonding moiré materials.

IF 15.7 1区 综合性期刊 Q1 MULTIDISCIPLINARY SCIENCES
Liya Wang, Jian Jiang, Siyi Liu, Shuying Lin, Jiajie Yan, YinBo Zhu, Jun Xia, Ruijie Wang, Chengyuan Wang, Chun Tang, Xiao Cheng Zeng
{"title":"Twisted bilayer Ice as a new class of hydrogen-bonding moiré materials.","authors":"Liya Wang, Jian Jiang, Siyi Liu, Shuying Lin, Jiajie Yan, YinBo Zhu, Jun Xia, Ruijie Wang, Chengyuan Wang, Chun Tang, Xiao Cheng Zeng","doi":"10.1038/s41467-025-63833-0","DOIUrl":null,"url":null,"abstract":"<p><p>Twisted bilayer van der Waals materials have become a transformative framework for the design of quantum and electronic devices, yet their counterparts, the twisted bilayer non-van der Waals materials, remain largely unexplored. Here, we report the first molecular-dynamics simulation evidence of the spontaneous formation of twisted bilayer ice with moiré patterns. Unlike the twisted bilayer van der Waals materials which can be produced by manually twisting one monolayer relative to another, twisted-bilayer-ice formation hinges on the structural adaptability of hydrogen bonds to achieve thermodynamic stability. First-principles molecular-dynamics simulations confirm the thermal stability of the twisted bilayer ice with two different moiré patterns, one with commensurate twist angle of 21.8° and another 27.8°. A phase diagram illustrates the stability region of twisted bilayer ice, providing guidance for future experimental validation. This work not only expands the family of two-dimensional ices but also advances the notion of twisted bilayer hydrogen-bonding materials, thereby offering opportunities to investigate emergent properties and potential applications of twisted bilayer non-van der Waals materials.</p>","PeriodicalId":19066,"journal":{"name":"Nature Communications","volume":"16 1","pages":"8762"},"PeriodicalIF":15.7000,"publicationDate":"2025-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Nature Communications","FirstCategoryId":"103","ListUrlMain":"https://doi.org/10.1038/s41467-025-63833-0","RegionNum":1,"RegionCategory":"综合性期刊","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"MULTIDISCIPLINARY SCIENCES","Score":null,"Total":0}
引用次数: 0

Abstract

Twisted bilayer van der Waals materials have become a transformative framework for the design of quantum and electronic devices, yet their counterparts, the twisted bilayer non-van der Waals materials, remain largely unexplored. Here, we report the first molecular-dynamics simulation evidence of the spontaneous formation of twisted bilayer ice with moiré patterns. Unlike the twisted bilayer van der Waals materials which can be produced by manually twisting one monolayer relative to another, twisted-bilayer-ice formation hinges on the structural adaptability of hydrogen bonds to achieve thermodynamic stability. First-principles molecular-dynamics simulations confirm the thermal stability of the twisted bilayer ice with two different moiré patterns, one with commensurate twist angle of 21.8° and another 27.8°. A phase diagram illustrates the stability region of twisted bilayer ice, providing guidance for future experimental validation. This work not only expands the family of two-dimensional ices but also advances the notion of twisted bilayer hydrogen-bonding materials, thereby offering opportunities to investigate emergent properties and potential applications of twisted bilayer non-van der Waals materials.

双扭层冰是一类新型的氢键流体材料。
扭曲双层范德华材料已经成为量子和电子器件设计的变革性框架,然而它们的对应物,扭曲双层非范德华材料,在很大程度上仍未被探索。在这里,我们报告了第一个分子动力学模拟证据,证明了具有波纹图案的扭曲双层冰的自发形成。不像扭曲的双层范德华材料,可以通过人工扭曲一个单层相对于另一个单层来生产,扭曲的双层冰的形成取决于氢键的结构适应性来实现热力学稳定性。第一性原理分子动力学模拟证实了两种不同畸变模式下扭曲双层冰的热稳定性,一种畸变角度为21.8°,另一种为27.8°。相图显示了扭曲双层冰的稳定区域,为进一步的实验验证提供了指导。这项工作不仅扩展了二维冰的家族,而且推进了扭曲双层氢键材料的概念,从而为研究扭曲双层非范德华材料的紧急性质和潜在应用提供了机会。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
求助全文
约1分钟内获得全文 求助全文
来源期刊
Nature Communications
Nature Communications Biological Science Disciplines-
CiteScore
24.90
自引率
2.40%
发文量
6928
审稿时长
3.7 months
期刊介绍: Nature Communications, an open-access journal, publishes high-quality research spanning all areas of the natural sciences. Papers featured in the journal showcase significant advances relevant to specialists in each respective field. With a 2-year impact factor of 16.6 (2022) and a median time of 8 days from submission to the first editorial decision, Nature Communications is committed to rapid dissemination of research findings. As a multidisciplinary journal, it welcomes contributions from biological, health, physical, chemical, Earth, social, mathematical, applied, and engineering sciences, aiming to highlight important breakthroughs within each domain.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
copy
已复制链接
快去分享给好友吧!
我知道了
右上角分享
点击右上角分享
0
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:604180095
Book学术官方微信