Perylenediimide-based Metal-Organic Frameworks: Structural, Electrochemical and Spectroelectrochemical Characterisation

IF 3.3 3区化学 Q2 CHEMISTRY, INORGANIC & NUCLEAR

Dalton Transactions Pub Date : 2025-10-02 DOI:10.1039/d5dt02244d

Joseph O. Ogar, Edward Stephen Davies, Asia Almuhana, Sarah Griffin, Matthew A. Addicoat, Stephen Argent, Neil R. Champness

引用次数: 0

Abstract

The electrochemical and spectroelectrochemical behaviour of metal-organic frameworks (MOFs) using a perylene diimide (PDI) based ligand is reported. Through suitable functionalisation, a PDI-based ligand is made soluble, allowing successful synthesis of two MOFs in combination with cobalt dicarboxylate paddlewheel secondary building units. Spectroelectrochemical techniques are used to probe the electrochemical and optical behaviour of the MOFs demonstrating that the properties of the perylene diimide are maintained by the MOF, facilitating electrochromic behaviour.

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基于苝酰亚胺的金属有机骨架：结构、电化学和光谱电化学表征

报道了以苝二酰亚胺（PDI）为配体的金属有机骨架（MOFs）的电化学和光谱电化学行为。通过适当的功能化，pdi为基础的配体是可溶的，允许成功合成两个MOFs与二羧酸钴桨轮二级建筑单元的组合。利用光谱电化学技术探测了MOF的电化学和光学行为，表明MOF保持了苝二亚胺的性质，促进了电致变色行为。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Dalton Transactions 化学-无机化学与核化学

CiteScore

6.60

自引率

7.50%

发文量

1832

审稿时长

1.5 months

期刊介绍： Dalton Transactions is a journal for all areas of inorganic chemistry, which encompasses the organometallic, bioinorganic and materials chemistry of the elements, with applications including synthesis, catalysis, energy conversion/storage, electrical devices and medicine. Dalton Transactions welcomes high-quality, original submissions in all of these areas and more, where the advancement of knowledge in inorganic chemistry is significant.