Linking Lattice Strain and Fractal Dimensions to Non-monotonic Volume Changes in Irradiated Nuclear Graphite

IF 24.5 Q1 CHEMISTRY, PHYSICAL
David J. Sprouster, Sean Fayfar, Durgesh K. Rai, Anne Campbell, Jan Ilavsky, Lance L. Snead, Boris Khaykovich
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Abstract

Graphite's resilience to high temperatures and neutron damage makes it vital for nuclear reactors, yet irradiation alters its microstructure, degrading key properties. We used small- and wide-angle X-ray scattering to study neutron-irradiated fine-grain nuclear graphite (Grade G347A) across varied temperatures and fluences. Results show significant shifts in internal strain and porosity, correlating with radiation-induced volume changes. Notably, porosity volume distribution (fractal dimensions) follows non-monotonic volume changes, suggesting a link to the Weibull distribution of fracture stress.

Abstract Image

辐照核石墨中晶格应变和分形维数与非单调体积变化的关系
石墨对高温和中子损伤的弹性使其对核反应堆至关重要,但辐照会改变其微观结构,降低其关键性能。利用小角和广角x射线散射研究了不同温度和影响下中子辐照的细粒核石墨(G347A级)。结果表明,内部应变和孔隙率的显著变化与辐射引起的体积变化有关。值得注意的是,孔隙度体积分布(分形维数)遵循非单调的体积变化,这表明孔隙度体积变化与破裂应力的威布尔分布有关。
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