Indications of Ferroelectric Behaviour Near Room Temperature in the Organic–Inorganic Hybrid Q₂CuBr₄

Abstract

A quinuclidinium-based copper bromide molecular ferroelectric, exhibiting a spontaneous polarization of Ps = 0.52 μC/cm², has been successfully synthesized. This compound undergoes an order–disorder phase transition at Tc = 295 K, associated with thermally induced rotational motion of the quinuclidinium cations. This transition results in pronounced changes in both the dielectric constant and thermal properties. The contributions of the organic and inorganic components, as well as their interactions, to the observed electrical and thermal behaviors are discussed using both experimental data and theoretical analysis.