Biomass-derived carbon dots embedded in B2O3 matrix with high proton density: A role as metal-free catalyst and hydrogel fillers for renewable energy applications

Abstract

Biomass-derived carbon dots (CDs) are emerging as promising candidates for fluorescent sensing and energy applications due to their tunable optical properties and environmental sustainability. However, their practical utility in renewable energy systems is hindered by low proton density, insufficient Lewis acid sites, poor ionic conductivity, and a strong tendency to aggregate. Herein, CDs from coffee waste are systematically embedded in a boron oxide (B₂O₃) matrix using boric acid (BA) as boron source via hydrothermal method. The resulting composite (BA₁CD) serves as a metal-free catalyst for hydrogen generation through sodium borohydride (NaBH₄) methanolysis. The B₂O₃ matrix induces Lewis acid sites in BA₁CD that activate methanol for the reaction. Consequently, BA₁CD exhibits remarkable catalytic activity for hydrogen generation, with a high hydrogen generation rate (139 L H₂ g⁻¹ min⁻¹) and low activation energy (26.2 kJ/mol). Furthermore, BA₁CD is incorporated as functional filler into polyacrylamide (PAM) hydrogel for triboelectric nanogenerator (TENG). Interestingly, B₂O₃ matrix promotes uniform dispersion of the CDs and prevents the aggregation of CD in the PAM hydrogel. Therefore, BA₁CD/PAM hydrogel demonstrates superior TENG performance with high output voltage (37.8 V) and current density (6.6 mA/m²), successfully powering various low-voltage everyday devices. This study provides a sustainable and multifunctional approach for biomass valorization toward advanced energy harvesting and storage technologies.