Discovery of Novel N-[(dimethylamino)methylene]thiourea (TUFA)-Functionalized Lignin for Efficient Cr(VI) Removal from Wastewater.

Abstract

This study developed a novel adsorbent for Cr (VI) removal from wastewater by grafting N-[(dimethylamino)methylene]thiourea (TUFA) onto lignin. The resulting TUFA-functionalized lignin adsorbent AL was comprehensively characterized using scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FT-IR), nuclear magnetic resonance (NMR), and X-ray photoelectron spectroscopy (XPS). Batch adsorption experiments systematically evaluated the influence of solution pH, contact time, temperature, initial Cr (VI) concentration, and adsorbent dosage. AL exhibited high adsorption capacity (593.9 mg g^-1 at 40 °C), attributed to its abundant nitrogen and sulfur-containing functional groups. Kinetic analysis revealed that the adsorption process followed pseudo-second-order kinetics. Equilibrium isotherm data were best described by the Langmuir model, indicating predominant monolayer chemisorption. Thermodynamic parameters demonstrated that Cr (VI) adsorption onto AL is spontaneous, endothermic, and entropy-driven. The adsorption mechanism involves membrane diffusion and intra-particle diffusion processes. This work successfully synthesized a stable, effective, and low-cost adsorbent (AL) using an amine agent incorporating both nitrogen and sulfur functional groups, offering a promising approach for treating Cr (VI)-contaminated wastewater.