Photocatalytic Hydrogen Production Performance of ZnCdS/CoWO4 Heterojunctions in the Reforming of Lignin Model Compounds.

Abstract

Biomass reforming under mild conditions for synergistic hydrogen production, driven by renewable solar energy, has rapidly emerged as a promising strategy that not only enables the efficient reutilization of biomass but also facilitates the generation of high-purity hydrogen. In this work, ZnCdS (ZCS) nanoparticles and CoWO₄ (CW) nanocrystals were assembled via a solvothermal method to construct a ZCS/CW S-type heterojunction composite. The resultant materials' physicochemical characteristics were methodically described. With lignin model compounds (PP-ol) and sodium lignosulfonate as substrates, the ZnCdS/CoWO₄-10% catalyst demonstrated a significant generation of hydrogen activity, producing hydrogen at rates of 223.30 μmol·g^-1·h^-1 and 140.28 μmol·g^-1·h^-1, respectively, according to experimental results. The formation of heterojunctions endows composite photocatalysts with higher hydrogen evolution rates compared to single-component catalysts. This is attributed to energy band bending at the interface of the heterojunction, which facilitates efficient charge separation while maintaining strong redox capabilities. High-value compounds like phenol and acetophenone were formed when the oxidation products in the post-reaction lignin model compound solution were subsequently analyzed using high-performance liquid chromatography. Additionally, a convincing mechanism for the catalytic reaction was suggested. It is expected that this study will offer a viable route for the creation of effective photocatalytic materials, high-value organic waste transformation, and sustainable hydrogen production.